3-Hydroxy-3-methylbutene
2-Methyl-3-buten-2-ol
Dimethylvinylmethanol
C5H10O
Molecular mass: 86.1
ICSC # 1719
CAS # 115-18-4
RTECS # EM9472000
UN # 1993
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Types of Hazard/ Exposure
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Acute Hazards/ Symptoms
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Prevention
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First Aid/ Fire Fighting
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FIRE
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Highly flammable.
Heating will cause rise in pressure with risk of bursting.
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NO open flames, NO sparks, and NO smoking.
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Carbon dioxide.
Dry powder.
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Explosion
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Vapour/air mixtures are explosive.
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Closed system, ventilation, explosion-proof electrical equipment and lighting.
Use non-sparking handtools.
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In case of fire: keep drums, etc., cool by spraying with water.
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Exposure
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Inhalation
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Cough.
Sore throat.
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Ventilation.
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Fresh air, rest.
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Skin
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Protective gloves.
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Rinse skin with plenty of water or shower.
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Eyes
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Redness.
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Safety spectacles.
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Rinse with plenty of water (remove contact lenses if easily possible).
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Ingestion
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Do not eat, drink, or smoke during work.
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Rinse mouth.
Give one or two glasses of water to drink.
Seek medical attention if you feel unwell
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Spillage Disposal
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Storage
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Packaging & Labelling
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Evacuate danger area!
Consult an expert!
Personal protection: complete protective clothing including self-contained breathing apparatus.
Remove all ignition sources.
Collect leaking liquid in sealable containers.
Absorb remaining liquid in sand or inert absorbent and remove to safe place.
Do NOT wash away into sewer.
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Fireproof.
Separated from oxidants.
Well closed.
Ventilation along the floor.
Store in an area without drain or sewer access.
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UN Hazard Class: 3
UN Packing Group: II
Signal: Danger
Flame-Excl mark
Highly flammable liquid and vapour
Harmful if swallowed
Causes eye irritation
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Important Data
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Physical State; Appearance:
COLOURLESS LIQUID
, WITH CHARACTERISTIC ODOUR.
Physical Dangers:
The vapour mixes well with air, explosive mixtures are formed easily.
Chemical Dangers:
Reacts violently with
oxidants.
Occupational Exposure Limits:
TLV not established.
MAK not established.
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Routes of Exposure:
The substance can be absorbed into the body
by ingestion.
Inhalation Risk:
No indication can be given about the rate in which a harmful concentration of this substance in the air is reached.
Effects of Short-Term Exposure:
The substance
is irritating to
the eyes
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Effects of Long-Term or Repeated Exposure:
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Physical Properties
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Boiling point: 97°C
Melting point: -28°C
Density: 0.8
g/cm3
Solubility in water, g/100 ml at 20°C: 19
(good)
Vapour pressure, kPa at 25°C: 3.13
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Relative vapour density (air = 1): 3.0
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.06
RIR (1.27)
Flashpoint: 10°C c.c.
Auto-ignition temperature: 380°C
Explosive limits, vol% in air: 1.5 - 9.4
Octanol/water partition coefficient as log Pow: 0.66
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Environmental Data
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N O T E S
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Transport Emergency Card: TEC (R)-30GF1-I+II.
NFPA Code: H1; F4; R0;
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ADDITIONAL INFORMATION
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ICSC: 1719
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2-METHYLBUT-3-EN-2-OL
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(C) IPCS, CEC, 1994
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IMPORTANT LEGAL NOTICE:
Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH,
the CEC or the IPCS is responsible for the use which might be made of this
information. This card contains the collective views of the IPCS Peer Review Committee and may
not reflect in all cases all the detailed requirements included in national legislation
on the subject. The user should verify compliance of the cards with the relevant legislation
in the country of use.
The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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