Benzoaphenanthrene
1,2-Benzophenanthrene
1,2,5,6-Dibenzonaphthalene
C18H12
Molecular mass: 228.3
ICSC # 1672
CAS # 218-01-9
RTECS # GC0700000
UN # 3077
EC # 601-048-00-0
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Types of Hazard/ Exposure
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Acute Hazards/ Symptoms
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Prevention
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First Aid/ Fire Fighting
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FIRE
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Combustible.
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NO open flames.
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Water spray.
Dry powder.
Foam.
Carbon dioxide.
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Explosion
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Finely dispersed particles form explosive mixtures in air.
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Prevent deposition of dust; closed system, dust explosion-proof electrical equipment and lighting.
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Exposure
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See EFFECTS OF LONG-TERM OR REPEATED Exposure.
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AVOID ALL CONTACT!
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Inhalation
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Local exhaust or breathing protection.
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Fresh air, rest.
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Skin
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Protective gloves.
Protective clothing.
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Remove contaminated clothes.
Rinse and then wash skin with water and soap.
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Eyes
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Safety goggles
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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Ingestion
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Do not eat, drink, or smoke during work.
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Rinse mouth.
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Spillage Disposal
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Storage
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Packaging & Labelling
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Personal protection: P3 filter respirator for toxic particles.
Do NOT let this chemical enter the environment.
Sweep spilled substance into sealable containers; if appropriate, moisten first to prevent dusting.
Carefully collect remainder,
then remove to safe place.
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Separated from strong oxidants,
Provision to contain effluent from fire extinguishing.
Store in an area without drain or sewer access.
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T symbol
N symbol
R: 45-68-50/53
S: 53-45-60-61
UN Hazard Class: 9
UN Packing Group: III
Signal: Warning
Health haz-Enviro
Suspected of causing cancer
Very toxic to aquatic life
Toxic to aquatic life with long lasting effects
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Important Data
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Physical State; Appearance:
COLOURLESS TO BEIGE CRYSTALS
OR POWDER
Physical Dangers:
Dust explosion possible if in powder or granular form, mixed with air.
Chemical Dangers:
The substance decomposes
on burning
producing
toxic fumes
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Reacts violently with strong oxidants.
Occupational Exposure Limits:
TLV: A3 (confirmed animal carcinogen with unknown relevance to humans); (ACGIH 2006).
MAK: skin absorption (H);
Carcinogen category: 2
(DFG 2007).
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Routes of Exposure:
The substance can be absorbed into the body
by inhalation of its aerosol,
through the skin
and
by ingestion.
Inhalation Risk:
A harmful concentration of airborne particles can be reached quickly when dispersed
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Effects of Short-Term Exposure:
Effects of Long-Term or Repeated Exposure:
This substance is possibly carcinogenic to humans.
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Physical Properties
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Boiling point: 448°C
Melting point: 254 - 256°C
Density: 1.3
g/cm3
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Solubility in water:
very poor
Octanol/water partition coefficient as log Pow: 5.9
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Environmental Data
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The substance is very toxic to aquatic organisms.
Bioaccumulation of this chemical may occur in seafood.
It is strongly advised that this substance does not enter the environment.
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N O T E S
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Depending on the degree of exposure, periodic medical examination is suggested.
Do NOT take working clothes home.
This substance does not usually occur as a pure substance but as a component of polyaromatic hydrocarbon (PAH) mixtures. Human population studies have associated PAH's exposure with cancer and cardiovascular diseases.
Transport Emergency Card: TEC (R)-90GM7-III
Card has been partially updated in January 2008: see Occupational Exposure Limits.
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ADDITIONAL INFORMATION
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ICSC: 1672
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CHRYSENE
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(C) IPCS, CEC, 1994
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IMPORTANT LEGAL NOTICE:
Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH,
the CEC or the IPCS is responsible for the use which might be made of this
information. This card contains the collective views of the IPCS Peer Review Committee and may
not reflect in all cases all the detailed requirements included in national legislation
on the subject. The user should verify compliance of the cards with the relevant legislation
in the country of use.
The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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