Dicyclopentadienyl iron
Di-2,4-cyclopentadien-1-yl iron
C10H10Fe / C5H5FeC5H5
Molecular mass: 186.0
ICSC # 1512
CAS # 102-54-5
RTECS # LK0700000
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Types of Hazard/ Exposure
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Acute Hazards/ Symptoms
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Prevention
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First Aid/
Fire Fighting
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FIRE
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Combustible.
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NO open flames.
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Powder, alcohol-resistant foam, water spray, carbon dioxide
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Explosion
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Exposure
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PREVENT DISPERSION OF DUST!
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•Inhalation
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Sore throat.
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Local exhaust or breathing protection.
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Fresh air, rest.
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•Skin
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Redness.
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Protective gloves.
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Rinse and then wash skin with water and soap.
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•Eyes
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Redness.
Pain.
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Safety goggles.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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•Ingestion
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Do not eat, drink, or smoke during work.
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Rinse mouth.
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Spillage Disposal
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Storage
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Packaging & Labelling
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Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting.
Personal protection: P1 filter respirator for inert particles.
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Separated from
strong oxidants.
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Important Data
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Physical State; Appearance:
ORANGE
CRYSTALS
, WITH CHARACTERISTIC ODOUR.
Physical Dangers:
Chemical Dangers:
On combustion, forms toxic fumes.
Reacts
violently with
ammonium perchlorate or tetranitromethane.
Reacts with mercury (II) nitrate.
Occupational Exposure Limits:
TLV: (as Fe) 10 mg/m3 as TWA; (ACGIH 2001).
MAK not established.
OSHA PEL: TWA 15 mg/m3 (total) TWA 5 mg/m3 (resp)
NIOSH REL: TWA 10 mg/m3 (total) TWA 5 mg/m3 (resp)
NIOSH IDLH: N.D. See: IDLH INDEX
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Routes of Exposure:
The substance can be absorbed into the body
by inhalation
and
by ingestion.
Inhalation Risk:
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed.
Effects of Short-Term Exposure:
May cause mechanical irritation.
Effects of Long-Term or Repeated Exposure:
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Physical
Properties
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Boiling point: 249°C
Sublimation point: above 100°C
Melting point: 173°C
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Solubility in water: none
Vapour pressure, Pa at 40°C: 4
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Environmental
Data
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N O T E S
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ADDITIONAL INFORMATION
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ICSC: 1512
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FERROCENE
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(C) IPCS, CEC, 1994
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IMPORTANT LEGAL NOTICE:
Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH,
the CEC or the IPCS is responsible for the use which might be made of this
information. This card contains the collective views of the IPCS Peer Review Committee and may
not reflect in all cases all the detailed requirements included in national legislation
on the subject. The user should verify compliance of the cards with the relevant legislation
in the country of use.
The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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