Cyclohexylamine, N,N-dimethyl-
Cyclohexyldimethylamine
N,N-Dimethylaminocyclohexane
C8H17N
Molecular mass: 127.26
ICSC # 1444
CAS # 98-94-2
RTECS # GX1198000
UN # 2264
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Types of Hazard/ Exposure
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Acute Hazards/ Symptoms
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Prevention
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First Aid/ Fire Fighting
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FIRE
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Flammable.
Gives off irritating or toxic fumes (or gases) in a fire.
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NO open flames, NO sparks, and NO smoking.
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Powder, alcohol-resistant foam, water spray, carbon dioxide.
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Explosion
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Above 42.2°C explosive vapour/air mixtures may be formed.
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Above 42.2°C use a closed system, ventilation, and explosion-proof electrical equipment.
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In case of fire: keep drums, etc., cool by spraying with water.
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Exposure
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PREVENT GENERATION OF MISTS!
AVOID ALL CONTACT!
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IN ALL CASES CONSULT A DOCTOR!
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Inhalation
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Sore throat.
Burning sensation.
Cough.
Laboured breathing.
Shortness of breath.
Symptoms may be delayed (see Notes).
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Ventilation, local exhaust, or breathing protection.
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Fresh air, rest.
Half-upright position.
Artificial respiration may be needed.
Refer for medical attention.
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Skin
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Redness.
Pain.
Skin burns.
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Protective gloves.
Protective clothing.
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First rinse with plenty of water, then remove contaminated clothes and rinse again.
Refer for medical attention.
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Eyes
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Redness.
Pain.
Severe deep burns.
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Face shield,
or eye protection in combination with breathing protection.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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Ingestion
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Burning sensation.
Abdominal pain.
Shock or collapse.
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Do not eat, drink, or smoke during work.
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Rinse mouth.
Give plenty of water to drink.
Do NOT induce vomiting.
Refer for medical attention.
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Spillage Disposal
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Storage
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Packaging & Labelling
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Collect leaking liquid in sealable containers.
Carefully collect remainder,
then remove to safe place.
Do NOT let this chemical enter the environment.
(Extra personal protection: filter respirator for organic gases and vapours.)
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Fireproof.
Separated from
strong acids,
food and feedstuffs
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Do not transport with food and feedstuffs.
UN Hazard Class: 8
UN Subsidiary Risks: 3
UN Packing Group: II
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Important Data
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Physical State; Appearance:
COLOURLESS
LIQUID
Physical Dangers:
Chemical Dangers:
The substance decomposes
on burning
producing
toxic fumes
including
nitrogen oxides
.
The substance is a medium strong base.
Occupational Exposure Limits:
TLV not established.
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Routes of Exposure:
The substance can be absorbed into the body
by inhalation,
through the skin
and
by ingestion.
Inhalation Risk:
No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C.
Effects of Short-Term Exposure:
The substance
is corrosive to
the skin,
the eyes
and
the respiratory tract.
Corrosive on ingestion.
Inhalation may cause lung oedema (see Notes).
The effects may be delayed.
Medical observation is indicated.
Effects of Long-Term or Repeated Exposure:
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Physical Properties
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Boiling point: 162-165°C
Melting point: -60°C
Relative density (water = 1) : 0.85
Solubility in water, g/100 ml: 20
Vapour pressure, kPa at 25°C: 0.4
Relative vapour density (air = 1): 4.4
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Relative density of the vapour/air-mixture at 20°C (air = 1): 1.01
Flash point: 42.2°C c.c.
Auto-ignition temperature: 215°C
Explosive limits, vol% in air: 3.6-19
Octanol/water partition coefficient as log Pow: 2.01
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Environmental Data
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The substance is harmful to aquatic organisms.
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N O T E S
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The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation is therefore essential.
Immediate administration of an appropriate inhalation therapy by a doctor or a person authorized by him/her, should be considered.
Transport Emergency Card: TEC (R)-80GCF1-II
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ADDITIONAL INFORMATION
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ICSC: 1444
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N,N-DIMETHYLCYCLOHEXYLAMINE
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(C) IPCS, CEC, 1994
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IMPORTANT LEGAL NOTICE:
Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH,
the CEC or the IPCS is responsible for the use which might be made of this
information. This card contains the collective views of the IPCS Peer Review Committee and may
not reflect in all cases all the detailed requirements included in national legislation
on the subject. The user should verify compliance of the cards with the relevant legislation
in the country of use.
The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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