Ether, 1-chloro-2,2,2-trifluoroethyl difluoromethyl
2-Chloro-2-(difluoromethoxy)-1,1,1-trifluoroethane
C3H2ClF5O
Molecular mass: 184.5
ICSC # 1435
CAS # 26675-46-7
RTECS # KN6799000
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Types of Hazard/ Exposure
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Acute Hazards/ Symptoms
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Prevention
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First Aid/ Fire Fighting
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FIRE
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Not combustible.
Gives off irritating or toxic fumes (or gases) in a fire.
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In case of fire in the surroundings: use appropriate extinguishing media.
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Explosion
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Exposure
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Inhalation
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Cough.
Sore throat.
Dizziness.
Drowsiness.
Headache.
Unconsciousness.
See Notes.
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Ventilation, local exhaust, or breathing protection.
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Fresh air, rest.
Artificial respiration may be needed.
Refer for medical attention.
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Skin
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Redness.
Dry skin.
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Protective gloves.
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Remove contaminated clothes.
Rinse and then wash skin with water and soap.
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Eyes
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Redness.
Pain.
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Safety spectacles
or
eye protection in combination with breathing protection.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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Ingestion
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(See Inhalation).
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Do not eat, drink, or smoke during work.
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Rinse mouth.
Refer for medical attention.
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Spillage Disposal
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Storage
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Packaging & Labelling
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Collect leaking and spilled liquid in sealable containers as far as possible.
Ventilation.
Absorb remaining liquid in sand or inert absorbent and remove to safe place.
Personal protection: self-contained breathing apparatus.
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Ventilation along the floor.
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Important Data
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Physical State; Appearance:
COLOURLESS LIQUID
Physical Dangers:
The vapour is heavier than air
and may accumulate in lowered spaces causing a deficiency of oxygen.
Chemical Dangers:
On contact with hot surfaces or flames this substance decomposes forming
corrosive fumes
including
phosgene
,
hydrogen chloride
and
hydrogen fluoride
Occupational Exposure Limits:
TLV not established.
MAK: IIb (not established but data is available) (DFG 2008).
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Routes of Exposure:
The substance can be absorbed into the body
by inhalation of its vapour
and
by ingestion.
Inhalation Risk:
A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20°C.
Effects of Short-Term Exposure:
The substance
is irritating to
the eyes
and
the skin
.
The vapour
is irritating to
the respiratory tract
.
The substance may cause effects on the
central nervous system
and
cardiovascular system
.
Exposure at high levels may result in unconsciousness.
Effects of Long-Term or Repeated Exposure:
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Physical Properties
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Boiling point: 48.5°C
Relative density (water = 1): 1.5
Solubility in water: poor
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Vapour pressure, kPa at 20°C: 32
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.2
Octanol/water partition coefficient as log Pow: 2.1
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Environmental Data
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N O T E S
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Check oxygen content before entering area.
High concentrations in the air cause a deficiency of oxygen with the risk of unconsciousness or death.
Forane is a trade name.
Card has been partly updated in April 2005. See sections Physical properties, Occupational Exposure Limits.
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ADDITIONAL INFORMATION
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ICSC: 1435
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ISOFLURANE
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(C) IPCS, CEC, 1994
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IMPORTANT LEGAL NOTICE:
Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH,
the CEC or the IPCS is responsible for the use which might be made of this
information. This card contains the collective views of the IPCS Peer Review Committee and may
not reflect in all cases all the detailed requirements included in national legislation
on the subject. The user should verify compliance of the cards with the relevant legislation
in the country of use.
The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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