Di(2-ethylhexyl)phosphate
Bis(2-ethylhexyl)hydrogen phosphate
Bis(isooctyl)phosphate
Dioctylphosphate
Bis(2-ethylhexyl)orthophosphoric acid
C16H35O4P
Molecular mass: 322.48
ICSC # 1412
CAS # 298-07-7
RTECS # TB7875000
UN # 1902
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Types of Hazard/ Exposure
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Acute Hazards/ Symptoms
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Prevention
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First Aid/ Fire Fighting
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FIRE
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Combustible.
Gives off irritating or toxic fumes (or gases) in a fire.
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NO open flames.
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Powder, alcohol-resistant foam, water spray, carbon dioxide.
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Explosion
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Exposure
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PREVENT GENERATION OF MISTS!
STRICT HYGIENE!
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IN ALL CASES CONSULT A DOCTOR!
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Inhalation
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Burning sensation.
Cough.
Sore throat.
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Local exhaust.
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Fresh air, rest.
Refer for medical attention.
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Skin
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Redness.
Burning sensation.
Pain.
Blisters.
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Protective gloves.
Protective clothing.
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Remove contaminated clothes.
Rinse and then wash skin with water and soap.
Refer for medical attention.
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Eyes
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Redness.
Pain.
Severe deep burns.
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Face shield.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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Ingestion
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Do not eat, drink, or smoke during work.
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Rinse mouth.
Do NOT induce vomiting.
Refer for medical attention.
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Spillage Disposal
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Storage
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Packaging & Labelling
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Collect leaking liquid in covered dry, plastic containers.
Absorb remaining liquid in sand or inert absorbent and remove to safe place.
(Extra personal protection: chemical protection suit including self-contained breathing apparatus.)
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Separated from
metals
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Do not transport with food and feedstuffs.
UN Hazard Class: 8
UN Packing Group: III
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Important Data
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Physical State; Appearance:
COLOURLESS OR AMBER LIQUID.
Physical Dangers:
Chemical Dangers:
The substance decomposes
on heating at 240°C
producing
toxic fumes
of
phosphorous oxides.
Attacks many metals forming flammable/explosive gas (hydrogen - see ICSC 0001).
Occupational Exposure Limits:
TLV not established.
MAK not established.
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Routes of Exposure:
The substance can be absorbed into the body
by inhalation of its aerosol
and
through the skin.
Inhalation Risk:
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying.
Effects of Short-Term Exposure:
The substance
is corrosive to
the eyes
and
the skin.
Effects of Long-Term or Repeated Exposure:
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Physical Properties
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Decomposes below boiling point at 240°C
Melting point: -50°C
Density: 0.96
g/cm3
Solubility in water, g/100 ml at 20°C: 0.21
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Vapour pressure, Pa at 20°C: <10
Flash point:
196°C o.c.
Octanol/water partition coefficient as log Pow: 2.67
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Environmental Data
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The substance is harmful to aquatic organisms.
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N O T E S
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Transport Emergency Card: TEC (R)-80GC3-III
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ADDITIONAL INFORMATION
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ICSC: 1412
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BIS(2-ETHYLHEXYL)PHOSPHATE
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(C) IPCS, CEC, 1994
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IMPORTANT LEGAL NOTICE:
Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH,
the CEC or the IPCS is responsible for the use which might be made of this
information. This card contains the collective views of the IPCS Peer Review Committee and may
not reflect in all cases all the detailed requirements included in national legislation
on the subject. The user should verify compliance of the cards with the relevant legislation
in the country of use.
The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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