O,O-Diethyl-O-{2-chloro-1-(2,4-dichlorophenyl)vinyl}phosphate
2-Chloro-1-(2,4-dichlorophenyl)vinyldiethyl phosphate
C12H14Cl3O4P
Molecular mass: 359,6
ICSC # 1305
CAS # 470-90-6
RTECS # TB8750000
UN # 3018
EC # 015-071-00-3
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Types of Hazard/ Exposure
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Acute Hazards/ Symptoms
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Prevention
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First Aid/
Fire Fighting
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FIRE
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Combustible.
Liquid formulations containing organic solvents may be flammable.
Gives off irritating or toxic fumes (or gases) in a fire.
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NO open flames.
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Powder, alcohol-resistant foam, water spray, carbon dioxide.
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Explosion
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Exposure
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PREVENT GENERATION OF MISTS!
STRICT HYGIENE!
AVOID Exposure OF ADOLESCENTS AND CHILDREN!
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IN ALL CASES CONSULT A DOCTOR!
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•Inhalation
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Pupillary constriction, muscle cramp, excessive salivation.
Sweating.
Nausea.
Dizziness.
Laboured breathing.
Headache.
Convulsions.
Unconciousness.
Symptoms may be delayed (see Notes).
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Local exhaust or breathing protection.
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Fresh air, rest.
Artificial respiration may be needed.
Refer for medical attention.
See Notes.
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•Skin
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MAY BE ABSORBED!
(See Inhalation).
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Protective gloves.
Protective clothing.
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Remove contaminated clothes.
Rinse and then wash skin with water and soap.
Refer for medical attention.
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•Eyes
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Blurred vision.
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Face shield
or
eye protection in combination with breathing protection.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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•Ingestion
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Abdominal cramps.
Diarrhoea.
Vomiting.
Weakness.
Convulsions.
(See Inhalation).
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Do not eat, drink, or smoke during work.
Wash hands before eating.
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Induce vomiting (ONLY IN CONSCIOUS PERSONS!).
Refer for medical attention.
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Spillage Disposal
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Storage
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Packaging & Labelling
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Collect leaking liquid in sealable containers.
Do NOT wash away into sewer.
Carefully collect remainder,
then remove to safe place.
Do NOT let this chemical enter the environment.
Chemical protection suit including self-contained breathing apparatus.
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Separated from
food and feedstuffs
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Well closed.
Stored in glass-lined or polyethylene-lined containers.
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Do not transport with food and feedstuffs.
Marine pollutant.
T+ symbol
N symbol
R: 24-28-50/53
S: 1/2-28-36/37-45-60-61
UN Hazard Class: 6.1
UN Packing Group: I
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Important Data
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Physical State; Appearance:
ORANGE TO BROWN LIQUID
, WITH CHARACTERISTIC ODOUR.
Physical Dangers:
Chemical Dangers:
The substance decomposes
on heating
and
on burning
producing toxic and corrosive fumes of hydrogen chloride, see - ICSC0163 and phosphorus oxides.
Attacks tin, brass, iron and steel.
Occupational Exposure Limits:
TLV not established.
MAK not established.
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Routes of Exposure:
The substance can be absorbed into the body
by inhalation and through the skin
and
by ingestion.
Inhalation Risk:
A harmful contamination of the air will not or will only very slowly be reached on evaporation of this substance at 20°C; on spraying or dispersing, however, much faster.
Effects of Short-Term Exposure:
The substance may cause effects on the the nervous system
, resulting in
convulsions
and
respiratory failure
.
Cholinesterase inhibitor.
Exposure may result in unconsciousness and death.
The effects may be delayed (see Notes).
Medical observation is indicated.
Effects of Long-Term or Repeated Exposure:
Cholinesterase inhibitor; cumulative effect is possible: see acute hazards/symptoms.
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Physical
Properties
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Boiling point at 0.07kPa: 167-170°C
Melting point: -19 to -23°C
Relative density (water = 1): 1.36
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Solubility in water: none
Vapour pressure, Pa at 20°C: <0.001 (0.53 mPa)
Octanol/water partition coefficient as log Pow: 3.82
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Environmental
Data
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The substance is very toxic to aquatic organisms.
The substance may cause long-term effects in the aquatic environment.
This substance does enter the environment under normal use. Great care, however, should be given to avoid any additional release, e.g. through inappropriate disposal.
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N O T E S
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Depending on the degree of exposure, periodic medical examination is suggested.
The symptoms of acute intoxication do not become manifest until 30 minutes to 6-12 hours.
Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.
If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s).
Carrier solvents used in commercial formulations may change physical and toxicological properties.
Do NOT take working clothes home.
Birlane, Dermaton, Sapecron, Steladone, Supona are trade names.
Card has been partly updated in April 2005. See section Emergency Response.
Transport Emergency Card: TEC (R)-61GT6-I
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ADDITIONAL INFORMATION
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ICSC: 1305
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CHLORFENVINPHOS
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(C) IPCS, CEC, 1994
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IMPORTANT LEGAL NOTICE:
Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH,
the CEC or the IPCS is responsible for the use which might be made of this
information. This card contains the collective views of the IPCS Peer Review Committee and may
not reflect in all cases all the detailed requirements included in national legislation
on the subject. The user should verify compliance of the cards with the relevant legislation
in the country of use.
The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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