ICSC:NENG1287 International Chemical Safety Cards (WHO/IPCS/ILO)

Thiocyanic acid, methylene ester
Methylene dithiocyanate
C₃H₂N₂S₂ / SCNCH₂SCN
Molecular mass: 130.2

ICSC #    1287
CAS #     6317-18-6
RTECS # XL1560000
EC #         615-020-00-0

Types of Hazard/ Exposure	Acute Hazards/ Symptoms	Prevention	First Aid/ Fire Fighting
FIRE	Gives off irritating or toxic fumes (or gases) in a fire.		In case of fire in the surroundings: all extinguishing agents allowed.
Explosion

Exposure		PREVENT DISPERSION OF DUST! STRICT HYGIENE!
•Inhalation	See Notes.	Local exhaust or breathing protection.	Fresh air, rest. Refer for medical attention.
•Skin	Redness. Pain.	Protective gloves. Protective clothing.	Remove contaminated clothes. Rinse and then wash skin with water and soap.
•Eyes	Redness. Pain.	Safety goggles or eye protection in combination with breathing protection.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
•Ingestion	See Notes.	Do not eat, drink, or smoke during work. Wash hands before eating.	Rinse mouth. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Rest.

Spillage Disposal

Storage

Packaging & Labelling

Sweep spilled substance into sealable containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. (Extra personal protection: complete protective clothing including self-contained breathing apparatus). Do NOT wash away into sewer.

Separated from food and feedstuffs . Well closed.

Do not transport with food and feedstuffs.
T+ symbol
N symbol
R: 25-26-34-43-50
S: 1/2-26-28-36/37/39-45-61

Important Data

Physical State; Appearance:
SOLID IN VARIOUS FORMS

Physical Dangers:

Chemical Dangers:
The substance decomposes on heating producing toxic fumes of nitrogen oxides and sulfur oxides . Reacts with strong acids causing toxic hazard.

Occupational Exposure Limits:
TLV not established.

Routes of Exposure:
The substance can be absorbed into the body by inhalation of its aerosol and by ingestion.

Inhalation Risk:
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly.

Effects of Short-Term Exposure:
The substance irritates the eyes and the skin. See Notes.

Effects of Long-Term or Repeated Exposure:
Repeated or prolonged contact may cause skin sensitization.

Physical
Properties

Melting point: 105-107°C
Solubility in water:
none

Environmental
Data

The substance is very toxic to aquatic organisms. Avoid release to the environment in circumstances different to normal use.

N O T E S

Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken. Effects of this compound are due to release of cyanide. Also consult

ICSC #0492 Hydrogen cyanide, liquefied.

ADDITIONAL INFORMATION

ICSC: 1287	METHYLENE BIS(THIOCYANATE)
(C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE:

Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.