3-(4-Chlorophenyl)-1-methoxy-1-methylurea
Urea, N'-(4-chlorophenyl)-N-methoxy-N-methyl-
3-(p-Chlorophenyl)-1-methoxy-1-methylurea
C9H11ClN2O2
Molecular mass: 214.6
ICSC # 1273
CAS # 1746-81-2
RTECS # YS6425000
EC # 006-032-00-1
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Types of Hazard/ Exposure
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Acute Hazards/ Symptoms
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Prevention
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First Aid/ Fire Fighting
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FIRE
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Combustible.
Liquid formulations containing organic solvents may be flammable.
Gives off irritating or toxic fumes (or gases) in a fire.
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NO open flames.
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Powder, water spray, foam, carbon dioxide.
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Explosion
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Risk of fire and explosion if formulations contain flammable/explosive solvents.
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Exposure
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PREVENT DISPERSION OF DUST!
AVOID Exposure OF ADOLESCENTS AND CHILDREN!
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Inhalation
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Local exhaust or breathing protection.
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Fresh air, rest.
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Skin
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Protective gloves.
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Rinse skin with plenty of water or shower.
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Eyes
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Safety spectacles.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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Ingestion
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Do not eat, drink, or smoke during work.
Wash hands before eating.
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Rinse mouth.
Rest.
Refer for medical attention.
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Spillage Disposal
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Storage
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Packaging & Labelling
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Do NOT wash away into sewer.
Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting.
Carefully collect remainder,
then remove to safe place.
Do NOT let this chemical enter the environment.
Personal protection:
chemical protection suit including self-contained breathing apparatus.
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Provision to contain effluent from fire extinguishing.
Separated from
food and feedstuffs
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Do not transport with food and feedstuffs.
Xn symbol
N symbol
R: 22-48/22-50/53
S: 2-22-60-61
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Important Data
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Physical State; Appearance:
COLOURLESS
CRYSTALS
Physical Dangers:
Chemical Dangers:
The substance decomposes
on heating or
on burning
producing
toxic fumes
including
hydrogen chloride
,
nitrogen oxides
.
Occupational Exposure Limits:
TLV not established.
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Routes of Exposure:
The substance can be absorbed into the body
by inhalation of its aerosol
and
by ingestion.
Inhalation Risk:
Evaporation at 20°C is negligible; a nuisance-causing concentration of airborne particles can, however, be reached quickly on spraying or when dispersed, especially if powdered.
Effects of Short-Term Exposure:
Effects of Long-Term or Repeated Exposure:
The substance may have effects on the blood
, resulting in
anaemia
.
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Physical Properties
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Melting point: 80-83°C
Solubility in water:
none
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Vapour pressure, Pa at 22°C: 0.02
Octanol/water partition coefficient as log Pow: 2.2
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Environmental Data
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The substance is harmful to aquatic organisms.
This substance may be hazardous to the environment; special attention should be given to algae and water plants.
Avoid release to the environment in circumstances different to normal use.
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N O T E S
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If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s).
Carrier solvents used in commercial formulations may change physical and toxicological properties.
Aresin, Arezin, Arezine, Arresin are trade names.
Card has been partly updated in October 2004. See sections Occupational Exposure Limits, EU classification, Emergency Response.
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ADDITIONAL INFORMATION
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ICSC: 1273
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MONOLINURON
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(C) IPCS, CEC, 1994
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IMPORTANT LEGAL NOTICE:
Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH,
the CEC or the IPCS is responsible for the use which might be made of this
information. This card contains the collective views of the IPCS Peer Review Committee and may
not reflect in all cases all the detailed requirements included in national legislation
on the subject. The user should verify compliance of the cards with the relevant legislation
in the country of use.
The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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