n-Nonane
2,2,5-Trimethylhexane
H3C(CH2)7CH3 / C9H20
Molecular mass: 128.2
ICSC # 1245
CAS # 111-84-2
RTECS # RA6115000
UN # 1920
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Types of Hazard/ Exposure
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Acute Hazards/ Symptoms
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Prevention
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First Aid/ Fire Fighting
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FIRE
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Flammable.
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NO open flames, NO sparks, and NO smoking.
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Powder, AFFF, foam, carbon dioxide.
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Explosion
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Above 31°C explosive vapour/air mixtures may be formed.
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Above 31°C use a closed system, ventilation, and explosion-proof electrical equipment.
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In case of fire: keep drums, etc., cool by spraying with water.
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Exposure
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PREVENT GENERATION OF MISTS!
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Inhalation
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Ataxia.
Convulsions.
Cough.
Unconsciousness.
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Ventilation, local exhaust, or breathing protection.
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Fresh air, rest.
Refer for medical attention.
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Skin
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Dry skin.
Redness.
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Protective gloves.
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Rinse and then wash skin with water and soap.
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Eyes
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Redness.
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Safety goggles,
or face shield.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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Ingestion
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Nausea.
Vomiting.
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Do not eat, drink, or smoke during work.
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Rinse mouth.
Refer for medical attention.
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Spillage Disposal
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Storage
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Packaging & Labelling
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Ventilation.
Absorb remaining liquid in dry sand or inert absorbent and remove to safe place.
(Extra personal protection: A filter respirator for organic vapour).
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Fireproof.
Separated from
strong oxidants.
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UN Hazard Class: 3
UN Packing Group: III
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Important Data
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Physical State; Appearance:
COLOURLESS LIQUID
, WITH CHARACTERISTIC ODOUR.
Physical Dangers:
The vapour is heavier than air.
Chemical Dangers:
Reacts with strong oxidants.
Occupational Exposure Limits:
TLV: 200 ppm; 1050 mg/m3 (as TWA) (ACGIH 1993-1994).
OSHA PEL: none
NIOSH REL: TWA 200 ppm (1050 mg/m3)
NIOSH IDLH: N.D. See: IDLH INDEX
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Routes of Exposure:
The substance can be absorbed into the body
by inhalation of its vapour and
by ingestion.
Inhalation Risk:
A harmful contamination of the air will not or will only very slowly be reached on evaporation of this substance at 20°C.
Effects of Short-Term Exposure:
The substance
irritates the eyes, the skin and the respiratory tract.
Swallowing the liquid may cause aspiration into the lungs with the risk of chemical pneumonitis.
The substance may cause effects on the central nervous system.
Exposure to the vapour could cause lowering of consciousness.
Effects of Long-Term or Repeated Exposure:
The liquid defats the skin.
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Physical Properties
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Boiling point: 150.8°C
Melting point: -51°C
Relative density (water = 1): 0.7
Solubility in water, g/100 ml at 20°C: 0.7
Vapour pressure, kPa at 20°C: 0.42
Relative vapour density (air = 1): 4.4
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Relative density of the vapour/air-mixture at 20°C (air = 1): <1.1
Flash point: 31°C c.c.
Auto-ignition temperature: 205°C
Explosive limits, vol% in air: 0.8-2.9
Octanol/water partition coefficient as log Pow: 5.65
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Environmental Data
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N O T E S
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Transport Emergency Card: TEC (R)-553
NFPA Code: H0; F3; R0
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ADDITIONAL INFORMATION
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ICSC: 1245
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NONANE
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(C) IPCS, CEC, 1994
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IMPORTANT LEGAL NOTICE:
Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH,
the CEC or the IPCS is responsible for the use which might be made of this
information. This card contains the collective views of the IPCS Peer Review Committee and may
not reflect in all cases all the detailed requirements included in national legislation
on the subject. The user should verify compliance of the cards with the relevant legislation
in the country of use.
The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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