4-(Methylamino)phenol
C7H9NO
Molecular mass: 123.2
ICSC # 1146
CAS # 150-75-4
RTECS # SL8225000
UN # 3077
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Types of Hazard/ Exposure
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Acute Hazards/ Symptoms
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Prevention
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First Aid/ Fire Fighting
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FIRE
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Combustible.
Gives off irritating or toxic fumes (or gases) in a fire.
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NO open flames.
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Powder, alcohol-resistant foam, water spray, carbon dioxide.
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Explosion
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Finely dispersed particles form explosive mixtures in air.
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Prevent deposition of dust; closed system, dust explosion-proof electrical equipment and lighting.
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Exposure
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PREVENT DISPERSION OF DUST!
AVOID ALL CONTACT!
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Inhalation
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Fresh air, rest.
Refer for medical attention.
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Skin
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Redness.
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Protective gloves.
Protective clothing.
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Remove contaminated clothes.
Rinse and then wash skin with water.
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Eyes
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Redness.
Pain.
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Safety goggles,
or eye protection in combination with breathing protection.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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Ingestion
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Do not eat, drink, or smoke during work.
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Rinse mouth.
Give plenty of water to drink.
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Spillage Disposal
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Storage
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Packaging & Labelling
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Do NOT let this chemical enter the environment.
Sweep spilled substance into covered containers; if appropriate, moisten first to prevent dusting.
Personal protection: P2 filter respirator for harmful particles.
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UN Hazard Class: 9
UN Packing Group: III
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Important Data
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Physical State; Appearance:
COLOURLESS
CRYSTALS
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Physical Dangers:
Dust explosion possible if in powder or granular form, mixed with air.
Chemical Dangers:
The substance decomposes
on burning
producing
toxic fumes
including
nitrogen oxides
.
Occupational Exposure Limits:
TLV not established.
MAK not established.
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Routes of Exposure:
The substance can be absorbed into the body
by ingestion.
Inhalation Risk:
No indication can be given whether a harmful concentration in the air will be reached.
Effects of Short-Term Exposure:
The substance
is irritating to
the eyes
and
the skin
.
Effects of Long-Term or Repeated Exposure:
Repeated or prolonged contact may cause skin sensitization.
The substance may have effects on the
blood
, resulting in lesions of blood cells.
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Physical Properties
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Melting point: 87°C
Solubility in water, g/100 ml at 25°C: 1.17
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Octanol/water partition coefficient as log Pow: 0.974
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Environmental Data
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The substance is very toxic to aquatic organisms.
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N O T E S
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Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken.
Some statements made on this card are based on information available for p-(Methylamino)phenol sulfate.
See ICSC 1528 p-(Methylamino)phenol sulfate.
Transport Emergency Card: TEC (R)-90GM7-III
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ADDITIONAL INFORMATION
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ICSC: 1146
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p-(METHYLAMINO)PHENOL
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(C) IPCS, CEC, 1994
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IMPORTANT LEGAL NOTICE:
Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH,
the CEC or the IPCS is responsible for the use which might be made of this
information. This card contains the collective views of the IPCS Peer Review Committee and may
not reflect in all cases all the detailed requirements included in national legislation
on the subject. The user should verify compliance of the cards with the relevant legislation
in the country of use.
The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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