ICSC:NENG1036 International Chemical Safety Cards (WHO/IPCS/ILO)

Oxalic acid, diammonium salt
Ethanedioic acid, diammonium salt
C₂H₈N₂O₄ / NH₄OOCCOONH₄
Molecular mass: 124.1

ICSC #    1036
CAS #     1113-38-8
RTECS # RO2750000
UN #        2811
EC #         607-007-00-3

Types of Hazard/ Exposure	Acute Hazards/ Symptoms	Prevention	First Aid/ Fire Fighting
FIRE	Combustible. Gives off irritating or toxic fumes (or gases) in a fire.	NO open flames.	Powder, water spray, foam, carbon dioxide.
Explosion

Exposure		PREVENT DISPERSION OF DUST!
•Inhalation	Cough. Sore throat (see Ingestion).	Local exhaust or breathing protection.	Fresh air, rest.
•Skin	Redness. Burning sensation. Pain. Blisters.	Protective gloves. Protective clothing.	Remove contaminated clothes. Rinse and then wash skin with water and soap.
•Eyes	Redness. Pain. Severe deep burns.	Safety goggles, or eye protection in combination with breathing protection.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
•Ingestion	Abdominal pain. Convulsions. Drowsiness. Dullness. Shock or collapse. Vomiting.	Do not eat, drink, or smoke during work.	Rinse mouth. Give plenty of water to drink. Rest. Refer for medical attention.

Spillage Disposal

Storage

Packaging & Labelling

Sweep spilled substance into sealable containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place (extra personal protection: P2 filter respirator for harmful particles).

Separated from food and feedstuffs, oxidants. Dry.

Do not transport with food and feedstuffs.
Note: A
Xn symbol
R: 21/22
S: 2-24/25
UN Hazard Class: 6.1
UN Packing Group: III

Important Data

Physical State; Appearance:
ODOURLESS, COLOURLESS, CRYSTALLINE POWDER.

Physical Dangers:

Chemical Dangers:
The substance decomposes on heating or on burning producing toxic and corrosive fumes including ammonia and nitrogen oxides. Reacts with oxidants.

Occupational Exposure Limits:
TLV not established.

Routes of Exposure:
The substance can be absorbed into the body by ingestion.

Inhalation Risk:
Evaporation at 20°C is negligible; a nuisance-causing concentration of airborne particles can, however, be reached quickly.

Effects of Short-Term Exposure:
The substance irritates the eyes, the skin and the respiratory tract. The substance may cause effects on the central nervous system and kidneys , resulting in impaired functions.

Effects of Long-Term or Repeated Exposure:
The substance may have effects on the kidneys.

Physical
Properties

Decomposes below melting point at see Notes
Relative density (water = 1): 1.50

Solubility in water: moderate

Environmental
Data

N O T E S

The physical properties are those of the monohydrate. Temperature of decomposition unknown in literature.

Transport Emergency Card: TEC (R)-61G12c

ADDITIONAL INFORMATION

ICSC: 1036	AMMONIUM OXALATE
(C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE:

Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.