ENDRIN ICSC: 1023 C12H8Cl6O Molecular mass: 380.9 ICSC #    1023 CAS #     72-20-8 RTECS # IO1575000 UN #        2761 EC #         602-051-00-X Types of Hazard/ Exposure Acute Hazards/ Symptoms Prevention First Aid/ Fire Fighting FIRE Not combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire. In case of fire in the surroundings: all extinguishing agents allowed. Explosion Exposure PREVENT DISPERSION OF DUST! STRICT HYGIENE! IN ALL CASES CONSULT A DOCTOR!  •Inhalation (See Ingestion). Local exhaust or breathing protection. Fresh air, rest. Refer for medical attention.  •Skin MAY BE ABSORBED! (See Ingestion). Protective gloves. Protective clothing. Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.  •Eyes Face shield or eye protection in combination with breathing protection if powder. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •Ingestion Dizziness. Weakness. Headache. Nausea. Vomiting. Convulsions. Do not eat, drink, or smoke during work. Wash hands before eating. Give a slurry of activated charcoal in water to drink. Rest. Refer for medical attention. Spillage Disposal Storage Packaging & Labelling Do NOT wash away into sewer. Sweep spilled substance into sealable containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. Do NOT let this chemical enter the environment. (Extra personal protection: chemical protection suit including self-contained breathing apparatus). Separated from food and feedstuffs . Well closed. Keep in a well-ventilated room. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing. Do not transport with food and feedstuffs. Severe marine pollutant. T+ symbol N symbol R: 24-28-50/53 S: 1/2-22-36/37-45-60-61 UN Hazard Class: 6.1 UN Packing Group: I ENDRIN ICSC: 1023 Important Data Physical State; Appearance: WHITE CRYSTALS . Physical Dangers: Chemical Dangers: The substance decomposes on heating above 245°C, producing hydrogen chloride , phosgene . Occupational Exposure Limits: TLV: 0.1 mg/m3 as TWA; (skin); A4 (not classifiable as a human carcinogen); (ACGIH 2008). MAK: 0.1 mg/m3 (Inhalable fraction); Peak limitation category: II(8); skin absorption (H); Pregnancy risk group: C; (DFG 2008). OSHA PEL: TWA 0.1 mg/m3 skin NIOSH REL: TWA 0.1 mg/m3 skin NIOSH IDLH: 2 mg/m3 See: 72208 Routes of Exposure: The substance can be absorbed into the body by inhalation, through the skin and by ingestion. Inhalation Risk: Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying or when dispersed, especially if powdered. Effects of Short-Term Exposure: The substance may cause effects on the central nervous system , resulting in convulsions and death. The effects may be delayed. Medical observation is indicated. Effects of Long-Term or Repeated Exposure: Physical Properties Decomposes below boiling point at 245°C Melting point: 200°C Density: 1.7 g/cm3 Solubility in water, g/100 ml at 25°C: none Vapour pressure, Pa at 25°C: negligible Octanol/water partition coefficient as log Pow: 5.34 Environmental Data The substance is very toxic to aquatic organisms. This substance may be hazardous to the environment; special attention should be given to honey bees , birds and mammals . It is strongly advised not to let the chemical enter into the environment because it persists in the environment. In the food chain important to humans, bioaccumulation takes place, specifically in fish and seafood . Avoid release to the environment in circumstances different to normal use. N O T E S If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s). Carrier solvents used in commercial formulations may change physical and toxicological properties. Do NOT take working clothes home. Transport Emergency Card: TEC (R)-61G41a NFPA Code: H3; F0; R; 0 Card has been partially updated in November 2008: see Occupational Exposure Limits, Storage. ADDITIONAL INFORMATION ICSC: 1023 ENDRIN (C) IPCS, CEC, 1994 IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.