2-Methyl butylacrylate
2-Propenoic acid, 2-methyl-, butyl ester
Butyl 2-methacrylate
Methacrylic acid, butyl ester
C8H14O2 / CH2C(CH3)COO(CH2)3CH3
Molecular mass: 142.2
ICSC # 1018
CAS # 97-88-1
RTECS # OZ3675000
UN # 2227
EC # 607-033-00-5
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Types of Hazard/ Exposure
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Acute Hazards/ Symptoms
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Prevention
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First Aid/
Fire Fighting
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FIRE
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Flammable.
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NO open flames, NO sparks, and NO smoking.
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Powder, AFFF, foam, carbon dioxide.
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Explosion
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Above 41°C explosive vapour/air mixtures may be formed.
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Above 41°C use a closed system, ventilation, and explosion-proof electrical equipment.
Prevent build-up of electrostatic charges (e.g., by grounding).
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In case of fire: keep drums, etc., cool by spraying with water.
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Exposure
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PREVENT GENERATION OF MISTS!
AVOID ALL CONTACT!
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•Inhalation
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Cough.
Shortness of breath.
Sore throat.
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Ventilation, local exhaust, or breathing protection.
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Fresh air, rest.
Half-upright position.
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•Skin
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Redness.
Pain.
(Further see Inhalation).
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Protective gloves.
Protective clothing.
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Remove contaminated clothes.
Rinse skin with plenty of water or shower.
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•Eyes
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Redness.
Pain.
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Safety goggles.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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•Ingestion
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Abdominal pain.
(Further see Inhalation).
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Do not eat, drink, or smoke during work.
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Rinse mouth.
Refer for medical attention.
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Spillage Disposal
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Storage
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Packaging & Labelling
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Collect leaking and spilled liquid in sealable sealable containers as far as possible.
Absorb remaining liquid in sand or inert absorbent and remove to safe place.
(Extra personal protection: filter respirator for organic gases and vapours).
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Fireproof.
Separated from
oxidants.
Cool.
Dry.
Keep in the dark.
Store only if stabilized.
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Note: D
Xi symbol
R: 10-36/37/38-43
S: 2
UN Hazard Class: 3
UN Packing Group: III
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Important Data
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Physical State; Appearance:
COLOURLESS LIQUID
, WITH CHARACTERISTIC ODOUR.
Physical Dangers:
As a result of flow, agitation, etc., electrostatic charges can be generated.
Chemical Dangers:
The substance may polymerize
due to heating,
under the influence of moisture, oxidants or light
with fire or explosion hazard.
Occupational Exposure Limits:
TLV not established.
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Routes of Exposure:
The substance can be absorbed into the body
by inhalation.
Inhalation Risk:
No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C.
Effects of Short-Term Exposure:
The substance
irritates
the eyes,
the skin and
the respiratory tract.
Effects of Long-Term or Repeated Exposure:
Repeated or prolonged contact may cause skin sensitization.
See Notes.
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Physical
Properties
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Boiling point: 163°C
Melting point: -25°C
Relative density (water = 1): 0.9
Solubility in water, g/100 ml: 0.6
Vapour pressure, Pa at 20°C: 270
Relative vapour density (air = 1): 4.9
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Relative density of the vapour/air-mixture at 20°C (air = 1): 1
Flash point: 41°C
Auto-ignition temperature: 290°C
Explosive limits, vol% in air: 2-8
Octanol/water partition coefficient as log Pow: 2.26-3.01
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Environmental
Data
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N O T E S
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Health effects of exposure to the substance have not been investigated adequately.
An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert.
Transport Emergency Card: TEC (R)-606A.
NFPA Code: H2; F2; R0.
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ADDITIONAL INFORMATION
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ICSC: 1018
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BUTYL METHACRYLATE
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(C) IPCS, CEC, 1994
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IMPORTANT LEGAL NOTICE:
Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH,
the CEC or the IPCS is responsible for the use which might be made of this
information. This card contains the collective views of the IPCS Peer Review Committee and may
not reflect in all cases all the detailed requirements included in national legislation
on the subject. The user should verify compliance of the cards with the relevant legislation
in the country of use.
The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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