TNPP
Phenol,nonyl-,phosphite (31)
C45H69O3P/(CH3(CH2)8C6H4O)3P
Molecular mass: 689
ICSC # 0964
CAS # 26523-78-4
UN # 3082
EC # 999-174-00-0
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Types of Hazard/ Exposure
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Acute Hazards/ Symptoms
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Prevention
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First Aid/ Fire Fighting
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FIRE
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Combustible.
Gives off irritating or toxic fumes (or gases) in a fire.
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NO open flames.
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Alcohol-resistant foam,
dry powder,
carbon dioxide.
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Explosion
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Exposure
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AVOID ALL CONTACT!
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Inhalation
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Ventilation.
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Fresh air, rest.
Seek medical attention if you feel unwell
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Skin
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Protective gloves.
Protective clothing.
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Rinse and then wash skin with water and soap.
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Eyes
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Safety spectacles
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Rinse with plenty of water (remove contact lenses if easily possible).
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Ingestion
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Do not eat, drink, or smoke during work.
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Rinse mouth.
Give one or two glasses of water to drink.
Seek medical attention if you feel unwell
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Spillage Disposal
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Storage
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Packaging & Labelling
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Personal protection:
chemical protection suit
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protective gloves.
Use face shield.
Collect leaking liquid in covered containers.
Absorb remaining liquid in sand or inert absorbent and remove to safe place.
Do NOT let this chemical enter the environment.
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Dry.
Store in an area without drain or sewer access.
Provision to contain effluent from fire extinguishing.
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UN Hazard Class: 9
UN Packing Group: III
Signal: Warning
Excl mark-Enviro
May cause an allergic skin reaction
Very toxic to aquatic life
Very toxic to aquatic life with long-lasting effects
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Important Data
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Physical State; Appearance:
COLOURLESS VISCOUS LIQUID
Physical Dangers:
Chemical Dangers:
On combustion, forms phosphorus oxides.
Occupational Exposure Limits:
TLV not established.
MAK not established.
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Routes of Exposure:
Inhalation Risk:
No indication can be given about the rate in which a harmful concentration of this substance in the air is reached.
Effects of Short-Term Exposure:
Effects of Long-Term or Repeated Exposure:
Repeated or prolonged contact may cause skin sensitization.
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Physical Properties
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Relative density (water = 1): 0.98
Solubility in water, g/100 ml: 4.1
see Notes
Vapour pressure, Pa at 25°C: 0.058
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Flash point: 207°C c.c.
Auto-ignition temperature: 440°C
Octanol/water partition coefficient as log Pow: 8
Viscosity, mm2/s at 25 °C: 6122
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Environmental Data
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The substance is very toxic to aquatic organisms.
The substance may cause long-term effects in the aquatic environment.
It is strongly advised that this substance does not enter the environment.
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N O T E S
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The substance may hydrolyse in contact with water forming phosphoric acid, nonylphenol and phenol.
See ICSC: 1008, 0309 and 0070.
Transport Emergency Card: TEC (R)-90GM6-III
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ADDITIONAL INFORMATION
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ICSC: 0964
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TRIS(NONYLPHENYL)PHOSPHITE
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(C) IPCS, CEC, 1994
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IMPORTANT LEGAL NOTICE:
Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH,
the CEC or the IPCS is responsible for the use which might be made of this
information. This card contains the collective views of the IPCS Peer Review Committee and may
not reflect in all cases all the detailed requirements included in national legislation
on the subject. The user should verify compliance of the cards with the relevant legislation
in the country of use.
The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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