2,4-Dinitro-6-(2-octyl)phenyl crotonate
2-Butenoic acid, 2(or 4)-isooctyl-4,6(or 2,6)dinitrophenyl ester
2,6(or 2,4)-Dinitro-4(or 6)octylphenyl crotonates in which octyl is a mixture of 1-methylheptyl, 1-ethylhexyl and 1-propylpentyl groups
DPC
C18H24N2O6
Molecular mass: 364.4
ICSC # 0881
CAS # 39300-45-3
RTECS # GQ5775000
EC # 609-023-00-6
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Types of Hazard/ Exposure
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Acute Hazards/ Symptoms
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Prevention
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First Aid/ Fire Fighting
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FIRE
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Combustible.
Gives off irritating or toxic fumes (or gases) in a fire.
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NO open flames.
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Powder, water spray, foam, carbon dioxide.
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Explosion
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In case of fire: keep drums, etc., cool by spraying with water.
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Exposure
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STRICT HYGIENE!
AVOID Exposure OF (PREGNANT) WOMEN!
AVOID Exposure OF ADOLESCENTS AND CHILDREN!
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Inhalation
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Laboured breathing.
See Ingestion.
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Ventilation, local exhaust, or breathing protection.
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Fresh air, rest.
Artificial respiration may be needed.
Refer for medical attention.
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Skin
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Pain.
Redness.
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Protective gloves.
Protective clothing.
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Remove contaminated clothes.
Rinse and then wash skin with water and soap.
Refer for medical attention.
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Eyes
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Safety goggles.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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Ingestion
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Nausea.
Vomiting.
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Do not eat, drink, or smoke during work.
Wash hands before eating.
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Rinse mouth.
Refer for medical attention.
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Spillage Disposal
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Storage
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Packaging & Labelling
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Collect leaking and spilled liquid in sealable containers as far as possible.
Absorb remaining liquid in sand or inert absorbent and remove to safe place.
Do NOT let this chemical enter the environment.
Personal protection: A/P2 filter respirator for organic vapour and harmful dust.
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Provision to contain effluent from fire extinguishing.
Separated from
food and feedstuffs
.
See Chemical Dangers.
Cool.
Well closed.
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Note: E
T symbol
N symbol
R: 61-20-22-38-43-48/22-50/53
S: 53-45-60-61
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Important Data
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Physical State; Appearance:
DARK BROWN LIQUID
Physical Dangers:
Chemical Dangers:
The substance decomposes
on burning
producing
toxic fumes
including
nitrogen oxides
.
The substance is a weak acid.
Reacts
with
strong oxidants
causing fire and explosion hazard.
May decompose when heated above 32°C.
Occupational Exposure Limits:
TLV not established.
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Routes of Exposure:
The substance can be absorbed into the body
by inhalation of its aerosol
and
by ingestion.
Inhalation Risk:
No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C.
Effects of Short-Term Exposure:
The substance
is irritating to
the skin
.
Effects of Long-Term or Repeated Exposure:
Repeated or prolonged contact may cause skin sensitization.
Animal tests show that this substance possibly causes malformations in human babies.
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Physical Properties
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Boiling point at 0.007kPa: 138-140°C
Relative density (water = 1): 1.10
Solubility in water:
none
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Vapour pressure, Pa at 20°C: negligible
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Environmental Data
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The substance is very toxic to aquatic organisms.
Avoid release to the environment in circumstances different to normal use.
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N O T E S
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Incompatible with oil, oil based sprays and lime sulfur mixture.
Carrier solvents used in commercial formulations may change physical and toxicological properties.
Caprane, Crotothane and Karathane are trade names.
Card has been partly updated in October 2004. See sections Occupational Exposure Limits, EU classification, Emergency Response.
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ADDITIONAL INFORMATION
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ICSC: 0881
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DINOCAP (ISOMER MIXTURE)
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(C) IPCS, CEC, 1994
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IMPORTANT LEGAL NOTICE:
Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH,
the CEC or the IPCS is responsible for the use which might be made of this
information. This card contains the collective views of the IPCS Peer Review Committee and may
not reflect in all cases all the detailed requirements included in national legislation
on the subject. The user should verify compliance of the cards with the relevant legislation
in the country of use.
The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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