Manganese ethylenebis(dithiocarbamate)(polymeric)complex with zinc salt
Manzeb
Manganese-zinc ethylenebis(dithiocarbamate)
C4H6N2S4Mn • C4H6N2S4Zn
Molecular mass: 541.0
ICSC # 0754
CAS # 8018-01-7
RTECS # ZB3200000
UN # 2210
EC # 006-076-00-1
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Types of Hazard/ Exposure
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Acute Hazards/ Symptoms
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Prevention
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First Aid/
Fire Fighting
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FIRE
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Combustible.
Gives off irritating or toxic fumes (or gases) in a fire.
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NO open flames.
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Powder, water spray, foam, carbon dioxide.
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Explosion
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Finely dispersed particles form explosive mixtures in air.
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Prevent deposition of dust; closed system, dust explosion-proof electrical equipment and lighting.
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Exposure
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PREVENT DISPERSION OF DUST!
AVOID ALL CONTACT!
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•Inhalation
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Cough.
Sore throat.
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Local exhaust or breathing protection.
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Fresh air, rest.
Refer for medical attention.
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•Skin
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Redness.
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Protective gloves.
Protective clothing.
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Remove contaminated clothes.
Rinse and then wash skin with water and soap.
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•Eyes
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Redness.
Pain.
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Safety goggles,
or eye protection in combination with breathing protection.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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•Ingestion
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Diarrhoea.
Nausea.
Vomiting.
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Do not eat, drink, or smoke during work.
Wash hands before eating.
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Rinse mouth.
Induce vomiting (ONLY IN CONSCIOUS PERSONS!).
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Spillage Disposal
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Storage
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Packaging & Labelling
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Do NOT wash away into sewer.
Sweep spilled substance into sealable containers.
Carefully collect remainder,
then remove to safe place.
(Extra personal protection: P2 filter respirator for harmful particles).
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Provision to contain effluent from fire extinguishing.
Separated from
acids,
food and feedstuffs
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Dry.
Keep in a well-ventilated room.
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Airtight.
Do not transport with food and feedstuffs.
Marine pollutant.
Xi symbol
R: 37-43
S: 2-8-24/25-46
UN Hazard Class: 4.2
UN Subsidiary Risks: 4.3
UN Packing Group: III
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Important Data
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Physical State; Appearance:
GREY
ISH-
YELLOW
POWDER
Physical Dangers:
Dust explosion possible if in powder or granular form, mixed with air.
Chemical Dangers:
The substance decomposes slowly
on heating
or
on contact with acids
and
moisture
producing toxic and
irritating fumes
including
sulfur oxides
,
nitrogen oxides
,zinc oxide, manganese oxide,
hydrogen sulfide
,
carbon sulfide
,ethylene thiuram sulfide, ethylene bisisothiocyanate, ethylene urea and 2-mercaptoimidazoline.
Occupational Exposure Limits:
TLV not established.
MAK not established.
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Routes of Exposure:
The substance can be absorbed into the body
by inhalation of its aerosol
and
by ingestion.
Inhalation Risk:
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed.
Effects of Short-Term Exposure:
The substance
is irritating to
the eyes
and
the respiratory tract
,
and
is mildly irritating to
the skin
.
Effects of Long-Term or Repeated Exposure:
Repeated or prolonged contact may cause skin sensitization.
See Notes.
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Physical
Properties
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Decomposes below melting point
Relative density (water = 1): 1.92
Solubility in water:
none
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Vapour pressure, Pa at 20°C: negligible
Flash point: 138°C o.c.
Octanol/water partition coefficient as log Pow: 1.33
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Environmental
Data
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The substance is toxic to aquatic organisms.
This substance does enter the environment under normal use. Great care, however, should be given to avoid any additional release, e.g. through inappropriate disposal.
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N O T E S
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Maneb, a related substance, may cause also other effects after long-term exposure.
If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s).
Carrier solvents used in commercial formulations may change physical and toxicological properties.
Aimcozeb, Crittox MZ, Dithane 945, Dithane M-45, Fore, Karamate, Mancozin, Manzate 200, Manzin, Nemispor, Penncozeb, Phytox MZ, Riozeb, Vondozeb Plus are trade names.
See ICSC1148, 2-Mercaptoimidazoline, a contaminant and breakdown product, ICSC0173 Maneb and ICSC0350 Zineb.
Transport Emergency Card: TEC (R)-42S2210
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ADDITIONAL INFORMATION
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ICSC: 0754
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MANCOZEB
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(C) IPCS, CEC, 1994
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IMPORTANT LEGAL NOTICE:
Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH,
the CEC or the IPCS is responsible for the use which might be made of this
information. This card contains the collective views of the IPCS Peer Review Committee and may
not reflect in all cases all the detailed requirements included in national legislation
on the subject. The user should verify compliance of the cards with the relevant legislation
in the country of use.
The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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