Glycerol trichlorohydrin
Allyl trichloride
C3H5Cl3 / CH2ClCHClCH2Cl
Molecular mass: 147.4
ICSC # 0683
CAS # 96-18-4
RTECS # TZ9275000
UN # 2810
EC # 602-062-00-X
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Types of Hazard/ Exposure
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Acute Hazards/ Symptoms
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Prevention
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First Aid/
Fire Fighting
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FIRE
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Combustible.
Gives off irritating or toxic fumes (or gases) in a fire.
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NO open flames.
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Powder, alcohol-resistant foam, water spray, carbon dioxide.
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Explosion
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Above 73°C explosive vapour/air mixtures may be formed.
Risk of fire and explosion on contact with metals.
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Above 73°C use a closed system, ventilation, and explosion-proof electrical equipment.
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In case of fire: keep drums, etc., cool by spraying with water.
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Exposure
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AVOID ALL CONTACT!
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IN ALL CASES CONSULT A DOCTOR!
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•Inhalation
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Cough.
Sore throat.
Headache.
Drowsiness.
Unconsciousness.
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Ventilation, local exhaust, or breathing protection.
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Fresh air, rest.
Refer for medical attention.
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•Skin
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Dry skin.
Redness.
Prickling.
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Protective gloves.
Protective clothing.
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Remove contaminated clothes.
Rinse skin with plenty of water or shower.
Refer for medical attention.
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•Eyes
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Redness.
Pain.
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Safety spectacles
or
eye protection in combination with breathing protection.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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•Ingestion
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Nausea.
Headache.
Vomiting.
Diarrhoea.
Drowsiness.
Unconsciousness.
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Do not eat, drink, or smoke during work.
Wash hands before eating.
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Rinse mouth.
Do NOT induce vomiting.
Give plenty of water to drink.
Refer for medical attention.
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Spillage Disposal
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Storage
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Packaging & Labelling
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Personal protection:
filter respirator for organic gases and vapours.
Collect leaking and spilled liquid in sealable containers as far as possible.
Absorb remaining liquid in sand or inert absorbent and remove to safe place.
Do NOT let this chemical enter the environment.
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Separated from
powdered metals
,
food and feedstuffs
.
Cool.
Keep in a well-ventilated room.
Store in an area without drain or sewer access.
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Do not transport with food and feedstuffs.
Marine pollutant.
Note: D
T symbol
R: 45-60-20/21/22
S: 53-45
UN Hazard Class: 6.1
UN Packing Group: III
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Important Data
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Physical State; Appearance:
COLOURLESS LIQUID
, WITH CHARACTERISTIC ODOUR.
Physical Dangers:
The vapour is heavier than air.
Chemical Dangers:
The substance decomposes
on burning
producing
toxic and corrosive fumes
.
Reacts
violently with
some
powdered metals
causing explosion hazard.
Occupational Exposure Limits:
TLV: 10 ppm as TWA; (skin); A3 (confirmed animal carcinogen with unknown relevance to humans); (ACGIH 2005).
MAK: skin absorption (H);
Carcinogen category: 2;
(DFG 2005).
OSHA PEL: TWA 50 ppm (300 mg/m3)
NIOSH REL: Ca TWA 10 ppm (60 mg/m3) skin See Appendix A
NIOSH IDLH: Ca 100 ppm See: 96184
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Routes of Exposure:
The substance can be absorbed into the body
by inhalation of its vapour,
through the skin
and
by ingestion.
Inhalation Risk:
A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20°C.
Effects of Short-Term Exposure:
The substance
is irritating to
the eyes
and
the respiratory tract
.
The substance may cause effects on the
liver
and
kidneys
, resulting in
impaired functions
.
Exposure at high levels may result in lowering of consciousness.
Effects of Long-Term or Repeated Exposure:
This substance is probably carcinogenic to humans.
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Physical
Properties
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Boiling point: 156°C
Melting point: -14°C
Relative density (water = 1): 1.39
Solubility in water, g/100 ml: 0.18 (very poor)
Vapour pressure, kPa at 20°C: 0.29
Relative vapour density (air = 1): 5.1
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Relative density of the vapour/air-mixture at 20°C (air = 1): 1.01
Flash point: 73°C c.c.
Auto-ignition temperature: 304°C
Explosive limits, vol% in air: 3.2-12.6
Octanol/water partition coefficient as log Pow: 2.27
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Environmental
Data
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The substance is harmful to aquatic organisms.
This substance may be hazardous to the environment; special attention should be given to ground water contamination.
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N O T E S
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Do NOT take working clothes home.
Card has been partly updated in October 2005. See section Occupational Exposure Limits.
Transport Emergency Card: TEC (R)-61GT1-III
NFPA Code: H3; F2; R0;
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ADDITIONAL INFORMATION
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ICSC: 0683
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1,2,3-TRICHLOROPROPANE
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(C) IPCS, CEC, 1994
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IMPORTANT LEGAL NOTICE:
Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH,
the CEC or the IPCS is responsible for the use which might be made of this
information. This card contains the collective views of the IPCS Peer Review Committee and may
not reflect in all cases all the detailed requirements included in national legislation
on the subject. The user should verify compliance of the cards with the relevant legislation
in the country of use.
The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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