Aluminium sodium oxide
Sodium aluminium dioxide
NaAlO2
Molecular mass: 82
ICSC # 0566
CAS # 1302-42-7
RTECS # BD1600000
UN # 2812
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Types of Hazard/ Exposure
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Acute Hazards/ Symptoms
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Prevention
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First Aid/ Fire Fighting
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FIRE
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Not combustible.
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In case of fire in the surroundings: all extinguishing agents allowed.
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Explosion
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Exposure
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AVOID ALL CONTACT!
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IN ALL CASES CONSULT A DOCTOR!
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Inhalation
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Burning sensation.
Sore throat.
Cough.
Laboured breathing.
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Local exhaust or breathing protection.
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Fresh air, rest.
Refer for medical attention.
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Skin
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Redness.
Pain.
Blisters.
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Protective gloves.
Protective clothing.
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Remove contaminated clothes.
Rinse skin with plenty of water or shower.
Refer for medical attention.
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Eyes
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Redness.
Pain.
Blurred vision.
Severe deep burns.
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Safety goggles,
face shield
or eye protection in combination with breathing protection.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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Ingestion
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Abdominal pain.
Burning sensation.
Shock or collapse.
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Do not eat, drink, or smoke during work.
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Rinse mouth.
Do NOT induce vomiting.
Refer for medical attention.
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Spillage Disposal
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Storage
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Packaging & Labelling
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Sweep spilled substance into containers.
Wash away remainder with plenty of water.
(Extra personal protection: P2 filter respirator for harmful particles).
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Separated from
food and feedstuffs
,
acids.
Dry.
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Do not transport with food and feedstuffs.
UN Hazard Class: 8
UN Packing Group: III
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Important Data
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Physical State; Appearance:
WHITE
,
HYGROSCOPIC
POWDER.
Physical Dangers:
Chemical Dangers:
The solution in water is a strong base, it reacts violently with acid and is corrosive to aluminium, tin and zinc.
Reacts
with
ammonium salts
causing fire hazard.
Occupational Exposure Limits:
TLV: (Borate compounds, inorganic) 2 mg/m3 as TWA, 6 mg/m3 as STEL; A4 (not classifiable as a human carcinogen); (ACGIH 2005).
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Routes of Exposure:
The substance can be absorbed into the body
by inhalation of its aerosol and
by ingestion.
Inhalation Risk:
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly
when dispersed
.
Effects of Short-Term Exposure:
The substance
is corrosive to
the eyes,
the skin and
the respiratory tract.
Corrosive on ingestion.
Medical observation is indicated.
Effects of Long-Term or Repeated Exposure:
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Physical Properties
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Melting point: 1650°C
Density: >1.5
g/cm3
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Solubility in water:
very good
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Environmental Data
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N O T E S
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Other UN numbers: 1819 (sodium aluminate, 80% solution): hazard class: 8, pack group: III. Other CAS number: 11138-49-1.
Transport Emergency Card: TEC (R)-80G09
Card has been partially updated in August 2007: see Occupational Exposure Limits.
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ADDITIONAL INFORMATION
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ICSC: 0566
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SODIUM ALUMINATE
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(C) IPCS, CEC, 1994
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IMPORTANT LEGAL NOTICE:
Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH,
the CEC or the IPCS is responsible for the use which might be made of this
information. This card contains the collective views of the IPCS Peer Review Committee and may
not reflect in all cases all the detailed requirements included in national legislation
on the subject. The user should verify compliance of the cards with the relevant legislation
in the country of use.
The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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