O,O-Dimethyl S-phthalimidomethyl phosphorodithioate
Phosphorodithioic acid, S-((1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)methyl) O,O-dimethyl ester
O,O-Dimethyl phosphorodithioate S-ester with N-(mercaptomethyl) phthalimide
C11H12NO4PS2
Molecular mass: 317.3
ICSC # 0543
CAS # 732-11-6
RTECS # TE2275000
UN # 2783
EC # 015-101-00-5
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Types of Hazard/ Exposure
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Acute Hazards/ Symptoms
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Prevention
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First Aid/
Fire Fighting
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FIRE
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Combustible.
Liquid formulations containing organic solvents may be flammable.
Gives off irritating or toxic fumes (or gases) in a fire.
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NO open flames.
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Powder, water spray, foam, carbon dioxide
.
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Explosion
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Risk of fire and explosion if formulations contain flammable/explosive solvents.
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Exposure
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PREVENT DISPERSION OF DUST!
AVOID Exposure OF ADOLESCENTS AND CHILDREN!
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•Inhalation
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Pupillary constriction, muscle cramp, excessive salivation.
Sweating.
Nausea.
Dizziness.
Laboured breathing.
Weakness.
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Ventilation (not if powder), local exhaust, or breathing protection.
Avoid inhalation of
dust
,
mist
.
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Fresh air, rest.
Refer for medical attention.
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•Skin
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MAY BE ABSORBED!
(See Inhalation).
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Protective gloves.
Protective clothing.
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Remove contaminated clothes.
Rinse and then wash skin with water and soap.
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•Eyes
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Redness.
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Safety goggles,
face shield,
or eye protection in combination with breathing protection.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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•Ingestion
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Abdominal cramps.
Vomiting.
Diarrhoea.
Convulsions.
Unconsciousness.
(Further see Inhalation).
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Do not eat, drink, or smoke during work.
Wash hands before eating.
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Rinse mouth.
Give a slurry of activated charcoal in water to drink.
Induce vomiting (ONLY IN CONSCIOUS PERSONS!).
Rest.
Refer for medical attention.
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Spillage Disposal
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Storage
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Packaging & Labelling
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Chemical protection suit including self-contained breathing apparatus.
Do NOT let this chemical enter the environment.
Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting.
Carefully collect remainder,
then remove to safe place.
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Provision to contain effluent from fire extinguishing.
Separated from
food and feedstuffs
.
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Do not transport with food and feedstuffs.
Marine pollutant.
Xn symbol
N symbol
R: 21/22-50/53
S: 2-22-36/37-60-61
UN Hazard Class: 6.1
UN Packing Group: III
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Important Data
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Physical State; Appearance:
COLOURLESS
TO OFF-
WHITE
CRYSTALS
, WITH CHARACTERISTIC ODOUR.
Physical Dangers:
Chemical Dangers:
The substance decomposes
on heating
or
on burning
producing toxic fumesincludingnitrogen oxides,phosphorous oxidesandsulfur oxides.
Occupational Exposure Limits:
TLV not established.
MAK not established.
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Routes of Exposure:
The substance can be absorbed into the body
by inhalation,
through the skin
and
by ingestion.
Inhalation Risk:
A harmful concentration of airborne particles can be reached quickly on spraying or when dispersed, especially if powdered.
Effects of Short-Term Exposure:
The substance may cause effects on the
nervous system
, resulting in
convulsions
and
respiratory depression
.
Cholinesterase inhibition.
The effects may be delayed.
Medical observation is indicated.
Effects of Long-Term or Repeated Exposure:
The substance may have effects on the
nervous system
, resulting in weakness.
Cholinesterase inhibitor; cumulative effect is possible: see Acute hazards/symptoms.
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Physical
Properties
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Decomposes below boiling point at >100°C
Melting point: 72°C
Density: 1.03
g/cm3
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Solubility in water, g/100 ml at 20°C: 0.003
Vapour pressure, Pa at 20°C: negligible
Octanol/water partition coefficient as log Pow: 2.83
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Environmental
Data
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The substance is very toxic to aquatic organisms.
This substance may be hazardous in the environment; special attention should be given to honey bees.
This substance does enter the environment under normal use. Great care, however, should be given to avoid any additional release, e.g. through inappropriate disposal.
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N O T E S
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Depending on the degree of exposure, periodic medical examination is suggested.
Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.
If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s).
Carrier solvents used in commercial formulations may change physical and toxicological properties.
Transport Emergency Card: TEC (R)-61GT7-III
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ADDITIONAL INFORMATION
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ICSC: 0543
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PHOSMET
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(C) IPCS, CEC, 1994
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IMPORTANT LEGAL NOTICE:
Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH,
the CEC or the IPCS is responsible for the use which might be made of this
information. This card contains the collective views of the IPCS Peer Review Committee and may
not reflect in all cases all the detailed requirements included in national legislation
on the subject. The user should verify compliance of the cards with the relevant legislation
in the country of use.
The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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