Acrylic acid, 2-ethylhexyl ester
Octyl acrylate
2-Propenoic acid, 2-ethylhexyl ester
2-Ethylhexyl 2-propenoate
C11H20O2 / CH2=CHCOOC8H17
Molecular mass: 184.3
ICSC # 0478
CAS # 103-11-7
RTECS # AT0855000
EC # 607-107-00-7
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Types of Hazard/ Exposure
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Acute Hazards/ Symptoms
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Prevention
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First Aid/ Fire Fighting
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FIRE
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Combustible.
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NO open flames.
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Powder, AFFF, foam, carbon dioxide.
Fine
water spray.
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Explosion
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Above 82°C explosive vapour/air mixtures may be formed.
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Above 82°C use a closed system, ventilation, and explosion-proof electrical equipment.
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In case of fire: keep drums, etc., cool by spraying with water.
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Exposure
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AVOID ALL CONTACT!
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Inhalation
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Cough.
Sore throat.
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Ventilation, local exhaust, or breathing protection.
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Fresh air, rest.
Refer for medical attention.
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Skin
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Redness.
Pain.
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Protective gloves.
Protective clothing.
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Remove contaminated clothes.
Rinse skin with plenty of water or shower.
Refer for medical attention.
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Eyes
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Redness.
Pain.
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Safety goggles,
or
or eye protection in combination with breathing protection.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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Ingestion
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Abdominal pain.
Diarrhoea.
Nausea.
Vomiting.
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Do not eat, drink, or smoke during work.
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Rinse mouth.
Give one or two glasses of water to drink.
Do NOT induce vomiting.
Refer for medical attention.
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Spillage Disposal
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Storage
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Packaging & Labelling
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Collect leaking liquid in covered containers.
Absorb remaining liquid in sand or inert absorbent and remove to safe place.
Do NOT let this chemical enter the environment.
Personal protection:
filter respirator for organic gases and vapours.
Chemical protection suit.
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Separated from
strong oxidants.
Cool.
Keep in the dark.
Store only if stabilized.
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Note: D
Xi symbol
R: 37/38-43
S: 2-36/37-46
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Important Data
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Physical State; Appearance:
COLOURLESS LIQUID
, WITH CHARACTERISTIC ODOUR.
Physical Dangers:
Vapours are uninhibited and may polymerize, blocking vents.
Chemical Dangers:
The substance will polymerize readily
under the influence of
light
,
heat
and
peroxides.
Reacts
violently with
strong oxidants
.
Occupational Exposure Limits:
TLV not established.
MAK: 5 ppm, 38 mg/m3
Peak limitation category: I(1)
sensitization of skin (Sh);
Pregnancy risk group: C
(DFG 2006).
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Routes of Exposure:
The substance can be absorbed into the body
by inhalation
and
by ingestion.
Inhalation Risk:
No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C.
Effects of Short-Term Exposure:
The substance
is irritating to
the eyes
,
the skin
and
the respiratory tract
.
Effects of Long-Term or Repeated Exposure:
Repeated or prolonged contact may cause skin sensitization.
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Physical Properties
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Boiling point: 213.5°C
Melting point: -90°C
Relative density (water = 1): 0.89
Solubility in water:
none
Vapour pressure, Pa at 20°C: 19
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Relative vapour density (air = 1): 6.35
Flash point: 82°C o.c.
Auto-ignition temperature: 252°C
Explosive limits, vol% in air: 0.8-6.4
Octanol/water partition coefficient as log Pow: 3.67
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Environmental Data
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The substance is harmful to aquatic organisms.
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N O T E S
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An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert.
Do NOT take working clothes home.
Card has been partly updated in October 2004. See sections Occupational Exposure Limits, EU classification, Emergency Response.
Card has been partly updated in October 2006. See sections Occupational Exposure Limits, Ingestion First Aid.
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ADDITIONAL INFORMATION
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ICSC: 0478
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2-ETHYLHEXYL ACRYLATE
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(C) IPCS, CEC, 1994
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IMPORTANT LEGAL NOTICE:
Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH,
the CEC or the IPCS is responsible for the use which might be made of this
information. This card contains the collective views of the IPCS Peer Review Committee and may
not reflect in all cases all the detailed requirements included in national legislation
on the subject. The user should verify compliance of the cards with the relevant legislation
in the country of use.
The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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