S-Ethyl dipropylthiocarbamate
Carbamothioic acid, dipropyl-, S-ethyl ester
S-Ethyl dipropylcarbamothioate
S-Ethyl-N,N-dipropylthiocarbamate
C9H19NOS / CH3CH2SC(O)N(CH2CH2CH3)2
Molecular mass: 189.3
ICSC # 0469
CAS # 759-94-4
RTECS # FA4550000
UN # 2992
EC # 006-030-00-0
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Types of Hazard/ Exposure
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Acute Hazards/ Symptoms
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Prevention
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First Aid/
Fire Fighting
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FIRE
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Combustible.
Liquid formulations containing organic solvents may be flammable.
Gives off irritating or toxic fumes (or gases) in a fire.
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NO open flames.
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Water spray, foam, powder, carbon dioxide.
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Explosion
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Exposure
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PREVENT GENERATION OF MISTS!
AVOID Exposure OF ADOLESCENTS AND CHILDREN!
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•Inhalation
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Dizziness.
Headache.
Nausea.
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Ventilation, local exhaust, or breathing protection.
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Fresh air, rest.
Refer for medical attention.
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•Skin
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Redness.
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Protective gloves.
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Remove contaminated clothes.
Rinse and then wash skin with water and soap.
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•Eyes
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Redness.
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Safety spectacles
or
eye protection in combination with breathing protection.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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•Ingestion
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(See Inhalation).
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Do not eat, drink, or smoke during work.
Wash hands before eating.
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Rinse mouth.
Rest.
Refer for medical attention.
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Spillage Disposal
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Storage
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Packaging & Labelling
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Collect leaking and spilled liquid in sealable containers as far as possible.
Absorb remaining liquid in sand or inert absorbent and remove to safe place.
Do NOT wash away into sewer.
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Provision to contain effluent from fire extinguishing.
Separated from
food and feedstuffs
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Ventilation along the floor.
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Do not transport with food and feedstuffs.
Xn symbol
R: 22
S: 2-23
UN Hazard Class: 6.1
UN Packing Group: III
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Important Data
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Physical State; Appearance:
COLOURLESS LIQUID
, WITH CHARACTERISTIC ODOUR.
Physical Dangers:
Chemical Dangers:
The substance decomposes
on heating
or
on burning
producing
toxic fumes
including
nitrogen oxides
and
sulfur oxides
.
Occupational Exposure Limits:
TLV not established.
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Routes of Exposure:
The substance can be absorbed into the body
by inhalation,
through the skin
and
by ingestion.
Inhalation Risk:
A harmful contamination of the air will not or will only very slowly be reached on evaporation of this substance at 20°C
; on spraying or dispersing, however, much faster.
Effects of Short-Term Exposure:
The substance may cause effects on the
central nervous system
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Effects of Long-Term or Repeated Exposure:
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Physical
Properties
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Boiling point: 232°C
Relative density (water = 1): 0.95
Solubility in water:
none
Vapour pressure, Pa at 25°C: 4.5
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Relative vapour density (air = 1): 6.5
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.00
Flash point: 116°C o.c.
Octanol/water partition coefficient as log Pow: 3.20
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Environmental
Data
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The substance is harmful to aquatic organisms.
This substance does enter the environment under normal use. Great care, however, should be given to avoid any additional release, e.g. through inappropriate disposal.
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N O T E S
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If the substance is formulated with solvents also consult the ICSCs of these materials.
Carrier solvents used in commercial formulations may change physical and toxicological properties.
The relation between odour and the occupational exposure limit cannot be indicated.
Alirox, Eptam, Eradicane, Genep, Niptan, Witox are trade names.
Card has been partly updated in October 2005. See section Emergency Response.
Transport Emergency Card: TEC (R)-61GT6-III
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ADDITIONAL INFORMATION
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ICSC: 0469
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EPTC
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(C) IPCS, CEC, 1994
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IMPORTANT LEGAL NOTICE:
Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH,
the CEC or the IPCS is responsible for the use which might be made of this
information. This card contains the collective views of the IPCS Peer Review Committee and may
not reflect in all cases all the detailed requirements included in national legislation
on the subject. The user should verify compliance of the cards with the relevant legislation
in the country of use.
The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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