Ethane, 1,1-dichloro-1-nitro-
C2H3Cl2NO2
Molecular mass: 143.9
ICSC # 0434
CAS # 594-72-9
RTECS # KI1050000
UN # 2650
EC # 610-002-00-9
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Types of Hazard/ Exposure
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Acute Hazards/ Symptoms
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Prevention
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First Aid/
Fire Fighting
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FIRE
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Flammable.
Gives off irritating or toxic fumes (or gases) in a fire.
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NO open flames, NO sparks, and NO smoking.
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Water spray, foam, powder, carbon dioxide
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Explosion
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Above 57.8°C explosive vapour/air mixtures may be formed.
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Above 57.8°C use a closed system, ventilation, and explosion-proof electrical equipment.
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In case of fire: keep drums, etc., cool by spraying with water.
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Exposure
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•Inhalation
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Cough.
Sore throat.
Laboured breathing.
Shortness of breath.
Symptoms may be delayed (see Notes).
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Ventilation, local exhaust, or breathing protection.
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Fresh air, rest.
Half-upright position.
Refer for medical attention.
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•Skin
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Redness.
Pain.
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Protective gloves.
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Remove contaminated clothes.
Rinse and then wash skin with water and soap.
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•Eyes
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Causes watering of the eyes.
Redness.
Pain.
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Safety goggles
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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•Ingestion
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Burning sensation.
Abdominal pain.
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Do not eat, drink, or smoke during work.
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Rinse mouth.
Refer for medical attention.
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Spillage Disposal
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Storage
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Packaging & Labelling
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Personal protection: self-contained breathing apparatus.
Collect leaking liquid in sealable metal containers.
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Fireproof.
Separated from
strong oxidants,
food and feedstuffs.
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T symbol
R: 23/24/25
S: 1/2-26-45
UN Hazard Class: 6.1
UN Packing Group: II
Signal: Danger
Flame-Skull
Flammable liquid and vapour
Toxic if swallowed
Fatal if inhaled vapour
May cause respiratory irritation
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Important Data
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Physical State; Appearance:
COLOURLESS LIQUID
, WITH PUNGENT ODOUR.
Physical Dangers:
Chemical Dangers:
On combustion, forms.
toxic gases
including
hydrogen chloride
,
nitrogen oxides
and
phosgene
.
Reacts violently with strong oxidants.
Attacks
rubber
and
some forms of
plastic
.
Occupational Exposure Limits:
TLV: 2 ppm as TWA (ACGIH 2006).
MAK: IIb (not established but data is available)
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Routes of Exposure:
The substance can be absorbed into the body
by ingestion
and
by inhalation of its vapour.
Inhalation Risk:
A harmful contamination of the air will be reached quickly on evaporation of this substance at 20°C; on spraying or dispersing, however, much faster.
Effects of Short-Term Exposure:
The substance
is irritating to
the eyes,
the skin
and
the respiratory tract.
Inhalation of vapours may cause lung oedema (see Notes).
Effects of Long-Term or Repeated Exposure:
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Physical
Properties
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Boiling point: 124°C
Relative density (water = 1): 1.4
Solubility in water: very poor
at 20°C
Vapour pressure, kPa at 20°C: 2
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Relative vapour density (air = 1): 5.0
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.0
Flash point: 57.8°C c.c.
Octanol/water partition coefficient as log Pow: 1.56
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Environmental
Data
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N O T E S
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Ethide is a trade name.
Environmental effects from the substance have not been investigated.
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation is therefore essential.
Transport Emergency Card: TEC (R)-G1GT1-II
NFPA Code: H2; F2; R3;
Card has been partially updated in August 2007: see GHS classification.
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ADDITIONAL INFORMATION
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ICSC: 0434
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1,1-DICHLORO-1-NITROETHANE
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(C) IPCS, CEC, 1994
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IMPORTANT LEGAL NOTICE:
Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH,
the CEC or the IPCS is responsible for the use which might be made of this
information. This card contains the collective views of the IPCS Peer Review Committee and may
not reflect in all cases all the detailed requirements included in national legislation
on the subject. The user should verify compliance of the cards with the relevant legislation
in the country of use.
The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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