Manganous sulphate monohydrate
MnSO4•H2O
Molecular mass: 169.0
ICSC # 0290
CAS # 10034-96-5
RTECS # OP0893500
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Types of Hazard/ Exposure
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Acute Hazards/ Symptoms
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Prevention
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First Aid/ Fire Fighting
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FIRE
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Not combustible.
Gives off irritating or toxic fumes (or gases) in a fire.
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In case of fire in the surroundings: use appropriate extinguishing media.
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Explosion
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Exposure
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PREVENT DISPERSION OF DUST!
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Inhalation
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Cough.
Laboured breathing.
Shortness of breath.
Sore throat.
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Local exhaust or breathing protection.
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Fresh air, rest.
Half-upright position.
Refer for medical attention.
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Skin
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Protective gloves.
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Eyes
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Redness.
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Safety spectacles
or
eye protection in combination with breathing protection if powder.
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First rinse with plenty of water (remove contact lenses if easily possible).
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Ingestion
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Sore throat.
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Do not eat, drink, or smoke during work.
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Rinse mouth.
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Spillage Disposal
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Storage
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Packaging & Labelling
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Personal protection: P2 filter respirator for harmful particles.
Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting.
Wash away remainder with plenty of water.
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Dry.
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Important Data
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Physical State; Appearance:
PINK HYGROSCOPIC CRYSTALS.
Physical Dangers:
Chemical Dangers:
The substance decomposes on heating producing sulfur oxides and manganese oxides.
Occupational Exposure Limits:
TLV: as Mn 0.2 mg/m3 as TWA; (ACGIH 2006).
MAK: (as Mn) (Inhalable fraction) 0.5 mg/m3
Pregnancy risk group: C;
(DFG 2005).
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Routes of Exposure:
The substance can be absorbed into the body
by inhalation of its aerosol
and
by ingestion.
Inhalation Risk:
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed, especially if powdered.
Effects of Short-Term Exposure:
Effects of Long-Term or Repeated Exposure:
The substance may have effects on the central nervous system.
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Physical Properties
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Relative density (water = 1): 2.95
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Solubility in water, g/100 ml: 39.3
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Environmental Data
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N O T E S
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Card has been partially updated in October 2006. See section Effects of Long-Term Exposure.
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ADDITIONAL INFORMATION
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ICSC: 0290
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MANGANESE SULPHATE MONOHYDRATE
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(C) IPCS, CEC, 1994
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IMPORTANT LEGAL NOTICE:
Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH,
the CEC or the IPCS is responsible for the use which might be made of this
information. This card contains the collective views of the IPCS Peer Review Committee and may
not reflect in all cases all the detailed requirements included in national legislation
on the subject. The user should verify compliance of the cards with the relevant legislation
in the country of use.
The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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