ICSC:NENG0242 International Chemical Safety Cards (WHO/IPCS/ILO)

Hexahydrobenzene
Hexamethylene
Hexanaphthene
C₆H₁₂
Molecular mass: 84.2

ICSC #    0242
CAS #     110-82-7
RTECS # GU6300000
UN #        1145
EC #         601-017-00-1

Types of Hazard/ Exposure	Acute Hazards/ Symptoms	Prevention	First Aid/ Fire Fighting
FIRE	Highly flammable.	NO open flames, NO sparks, and NO smoking.	Water spray, alcohol-resistant foam , carbon dioxide , powder .
Explosion	Vapour/air mixtures are explosive. Heating will cause rise in pressure with risk of bursting.	Closed system, ventilation, explosion-proof electrical equipment and lighting. Do NOT use compressed air for filling, discharging, or handling. Use non-sparking handtools. Prevent build-up of electrostatic charges (e.g., by grounding).	In case of fire: keep drums, etc., cool by spraying with water.

Exposure
•Inhalation	Cough. Dizziness. Drowsiness. Headache. Nausea.	Ventilation, local exhaust, or breathing protection.	Fresh air, rest. ected at peer review 2008 - not toxic
•Skin	Redness.	Protective gloves.	Remove contaminated clothes. Rinse and then wash skin with water and soap.
•Eyes	Redness.	Safety goggles or eye protection in combination with breathing protection. .	Rinse with plenty of water (remove contact lenses if easily possible).
•Ingestion	Abdominal pain. Nausea. Vomiting. (Further see Inhalation).	Do not eat, drink, or smoke during work.	Rinse mouth. Do NOT induce vomiting. Refer for medical attention.

Spillage Disposal

Storage

Packaging & Labelling

Evacuate danger area! Consult an expert! Remove all ignition sources. Personal protection: self-contained breathing apparatus. Do NOT let this chemical enter the environment. Ventilation. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT wash away into sewer.

Fireproof. Provision to contain effluent from fire extinguishing. Separated from strong oxidants, Store in an area without drain or sewer access.

Note: 4
F symbol
Xn symbol
N symbol
R: 11-38-65-67-50/53
S: 2-9-16-25-33-60-61-62
UN Hazard Class: 3
UN Packing Group: II
Signal: Danger
Flame-Excl mark-Health haz-Enviro
Highly flammable liquid and vapour
May be fatal if swallowed and enters airways
Causes eye irritation
Causes mild skin irritation
May cause drowsiness or dizziness
Very toxic to aquatic life
Very toxic to aquatic life with long lasting effects

Important Data

Physical State; Appearance:
COLOURLESS LIQUID , WITH CHARACTERISTIC ODOUR.

Physical Dangers:
The vapour is heavier than air and may travel along the ground; distant ignition possible. As a result of flow, agitation, etc., electrostatic charges can be generated.

Chemical Dangers:
Heating may cause violent combustion or explosion. Reacts with strong oxidants.

Occupational Exposure Limits:
TLV: 100 ppm as TWA; (ACGIH 2007).
EU OEL: 200 ppm, 700 mg/m³ as TWA (EU 2006).
OSHA PEL: TWA 300 ppm (1050 mg/m³)
NIOSH REL: TWA 300 ppm (1050 mg/m³)
NIOSH IDLH: 1300 ppm 10%LEL See: 110827

Routes of Exposure:

Inhalation Risk:
A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20°C.

Effects of Short-Term Exposure:
The substance is mildly irritating to the eyes, the skin and the respiratory tract . If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis. Exposure far above the OEL could cause lowering of consciousness.

Effects of Long-Term or Repeated Exposure:
The liquid defats the skin. Repeated or prolonged contact with skin may cause dermatitis.

Physical
Properties

Boiling point: 81°C
Melting point: 7°C
Relative density (water = 1): 0.8
Solubility in water, g/100 ml at 25°C: 0.0058
(very poor)
Vapour pressure, kPa at 20°C: 10.3
Relative vapour density (air = 1): 2.9

Relative density of the vapour/air-mixture at 20°C (air = 1): 1.2
Flash point: -18°C c.c.
Auto-ignition temperature: 260°C
Explosive limits, vol% in air: 1.3-8.4
Octanol/water partition coefficient as log Pow: 3.4
Viscosity, mm²/s at 26 °C: 1.26x10-6

Environmental
Data

The substance is very toxic to aquatic organisms. The substance may cause long-term effects in the aquatic environment. It is strongly advised that this substance does not enter the environment.

N O T E S

The odour warning when the exposure limit value is exceeded is insufficient.

Transport Emergency Card: TEC (R)-30S1145 or 30GF1-I+II
NFPA Code: H 1; F 3; R 0;

ADDITIONAL INFORMATION

ICSC: 0242	CYCLOHEXANE
(C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE:

Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.