ICSC:NENG0160 International Chemical Safety Cards (WHO/IPCS/ILO)

N-(Phosphonomethyl)glycine
C₃H₈NO₅P / HOOCCH₂NHCH₂PO(OH)₂
Molecular mass: 169.1

ICSC #    0160
CAS #     1071-83-6
RTECS # MC1075000
EC #         607-315-00-8

Types of Hazard/ Exposure	Acute Hazards/ Symptoms	Prevention	First Aid/ Fire Fighting
FIRE	Combustible. Gives off irritating or toxic fumes (or gases) in a fire.	NO open flames, NO sparks, and NO smoking.	Powder, alcohol-resistant foam, water spray, carbon dioxide.
Explosion	Finely dispersed particles form explosive mixtures in air.	Prevent build-up of electrostatic charges (e.g., by grounding). Prevent deposition of dust; closed system, dust explosion-proof electrical equipment and lighting.

Exposure		PREVENT DISPERSION OF DUST!
•Inhalation	Cough.	Avoid inhalation of fine dust and mist.	Fresh air, rest.
•Skin	Redness.	Protective gloves.	Remove contaminated clothes. Rinse and then wash skin with water and soap.
•Eyes	Redness. Pain.	Safety goggles.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
•Ingestion	Burning sensation in the throat and chest.	Do not eat, drink, or smoke during work. Wash hands before eating.	Rinse mouth. Do NOT induce vomiting.

Spillage Disposal

Storage

Packaging & Labelling

Personal protection: P2 filter respirator for harmful particles. Sweep spilled substance into plastic containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. Do NOT let this chemical enter the environment.

Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs . Well closed. Do NOT store in galvanized steel or unlined steel containers. Store in an area without drain or sewer access.

Do not transport with food and feedstuffs.
Xi symbol
N symbol
R: 41-51/53
S: 2-26-39-61

Important Data

Physical State; Appearance:
COLOURLESS CRYSTALS

Physical Dangers:
Dust explosion possible if in powder or granular form, mixed with air. If dry, it can be charged electrostatically by swirling, pneumatic transport, pouring, etc.

Chemical Dangers:
The substance decomposes on heating producing toxic fumes including nitrogen oxides , phosphorus oxides . Attacks iron and galvanized steel.

Occupational Exposure Limits:
TLV not established.

Routes of Exposure:

Inhalation Risk:
A harmful concentration of airborne particles can be reached quickly on spraying.

Effects of Short-Term Exposure:
The substance is severely irritating to the eyes and is mildly irritating to the skin.

Effects of Long-Term or Repeated Exposure:

Physical
Properties

Melting point (decomposes): below 234°C
Density: 1.7
g/cm³

Solubility in water, g/100 ml at 25°C: 1.2
Vapour pressure, Pa at 20°C: negligible
Octanol/water partition coefficient as log Pow: -1.0

Environmental
Data

The substance is toxic to aquatic organisms. This substance does enter the environment under normal use. Great care, however, should be given to avoid any additional release, e.g. through inappropriate disposal.

N O T E S

Sodium, potassium and amine salts are readily soluble in water. Roundup (for the monoisopropyl ammonium salt) and Polado (for the sesquisodium salt) are trade names. Carrier solvents used in commercial formulations may change physical and toxicological properties.

ADDITIONAL INFORMATION

ICSC: 0160	GLYPHOSATE
(C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE:

Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.