1,4-Bis (2,3-epoxypropoxy) butane
1,4-Butane diglycidyl ether
C10H18O4
Molecular mass: 202.3
ICSC # 0110
CAS # 2425-79-8
RTECS # EJ5100000
EC # 603-072-00-7
|
|
Types of Hazard/ Exposure
|
Acute Hazards/ Symptoms
|
Prevention
|
First Aid/ Fire Fighting
|
|
FIRE
|
Combustible.
|
NO open flames.
|
Powder,
alcohol-resistant foam,
carbon dioxide.
|
|
Explosion
|
|
|
|
|
|
|
Exposure
|
|
AVOID ALL CONTACT!
|
|
|
Inhalation
|
Cough.
Sore throat.
|
Ventilation, local exhaust, or breathing protection.
|
Fresh air, rest.
|
|
Skin
|
Redness.
Pain.
|
Protective gloves.
Protective clothing.
|
Remove contaminated clothes.
Rinse and then wash skin with water and soap.
Refer for medical attention if skin irritation occurs.
|
|
Eyes
|
Redness.
Pain.
|
Safety goggles.
or
eye protection in combination with breathing protection.
|
Rinse with plenty of water (remove contact lenses if easily possible).
Refer immediately for medical attention.
|
|
Ingestion
|
Burning sensation.
Sore throat.
|
Do not eat, drink, or smoke during work.
|
Rinse mouth.
Give one or two glasses of water to drink.
Seek medical attention if you feel unwell.
|
|
Spillage Disposal
|
Storage
|
Packaging & Labelling
|
Personal protection: filter respirator for organic gases and vapours adapted to the airbone concentration of the substance.
Collect leaking liquid in sealable containers.
Wash away remainder with plenty of water.
|
Separated from
strong oxidants,
acids
and
bases.
Cool.
Keep in the dark.
Ventilation along the floor.
|
Xn symbol
R: 20/21-36/38-43
S: 2-26-28-37/39
Signal: Warning
Excl mark
Harmful if swallowed
Harmful in contact with skin
Causes skin irritation
Causes serious eye irritation
May cause allergic skin reaction
May cause respiratory irritation
|
|
|
|
Important Data
|
Physical State; Appearance:
COLOURLESS
TO YELLOW
LIQUID.
Physical Dangers:
Chemical Dangers:
The substance can presumably form explosive peroxides.
Reacts
with
strong oxidants,
acids
and
bases.
Occupational Exposure Limits:
TLV not established.
MAK: sensitization of skin (Sh); (DFG 2007).
|
Routes of Exposure:
The substance can be absorbed into the body
through the skin
and
by ingestion.
Inhalation Risk:
No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C.
Effects of Short-Term Exposure:
The substance
is irritating to
the respiratory tract.
The substance
is severely irritating to
the eyes
and
the skin.
Effects of Long-Term or Repeated Exposure:
Repeated or prolonged contact may cause skin sensitization.
|
|
Physical Properties
|
Boiling point: 266°C
Density: 1.1
g/cm3
Solubility in water: miscible
Vapour pressure, kPa at 20°C: 1.3
|
Relative vapour density (air = 1): 7.0
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.08
Flash point: 129°C
Octanol/water partition coefficient as log Pow: -0.15
|
|
Environmental Data
|
|
|
N O T E S
|
|
Check for peroxides prior to distillation; eliminate if found.
|
|
ADDITIONAL INFORMATION
|
|
|
|
ICSC: 0110
|
1,4-BUTANEDIOL DIGLYCIDYL ETHER
|
|
(C) IPCS, CEC, 1994
|
|
|
IMPORTANT LEGAL NOTICE:
Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH,
the CEC or the IPCS is responsible for the use which might be made of this
information. This card contains the collective views of the IPCS Peer Review Committee and may
not reflect in all cases all the detailed requirements included in national legislation
on the subject. The user should verify compliance of the cards with the relevant legislation
in the country of use.
The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
|
|
|