ICSC:NENG0106 International Chemical Safety Cards (WHO/IPCS/ILO)

Diphenyl
Phenylbenzene
Dibenzene
C₁₂H₁₀ / C₆H₅C₆H₅
Molecular mass: 154.2

ICSC #    0106
CAS #     92-52-4
RTECS # DU8050000
UN #        3077
EC #         601-042-00-8

Types of Hazard/ Exposure	Acute Hazards/ Symptoms	Prevention	First Aid/ Fire Fighting
FIRE	Combustible.	NO open flames.	water spray, foam, powder, carbon dioxide
Explosion	Finely dispersed particles form explosive mixtures in air.	Prevent deposition of dust; closed system, dust explosion-proof electrical equipment and lighting. Prevent build-up of electrostatic charges (e.g., by grounding).

Exposure		PREVENT DISPERSION OF DUST!
•Inhalation	Cough. Nausea. Vomiting.	Avoid inhalation of fine dust and mist. Local exhaust or breathing protection.	Fresh air, rest. Refer for medical attention.
•Skin	Redness.	Protective gloves.	Remove contaminated clothes. Rinse and then wash skin with water and soap.
•Eyes	Redness. Pain.	Safety goggles or eye protection in combination with breathing protection if powder.	Rinse with plenty of water (remove contact lenses if easily possible).
•Ingestion	(Further see Inhalation).	Do not eat, drink, or smoke during work. Wash hands before eating.	Rinse mouth. Refer for medical attention.

Spillage Disposal

Storage

Packaging & Labelling

Personal protection: A/P2 filter respirator for organic vapour and harmful dust. Sweep spilled substance into sealable containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. Do NOT let this chemical enter the environment.

Separated from food and feedstuffs, oxidants . Provision to contain effluent from fire extinguishing. Store in an area without drain or sewer access.

Do not transport with food and feedstuffs.
Xi symbol
N symbol
R: 36/37/38-50/53
S: 2-23-60-61
UN Hazard Class: 9
UN Packing Group: III
Signal: Warning
Health haz-Enviro
Causes eye irritation
May cause damage to liver and nervous system through prolonged or repeated exposure if inhaled
Very toxic to aquatic life

Important Data

Physical State; Appearance:
WHITE CRYSTALS OR FLAKES , WITH CHARACTERISTIC ODOUR.

Physical Dangers:
Dust explosion possible if in powder or granular form, mixed with air.

Chemical Dangers:
Reacts with oxidants .

Occupational Exposure Limits:
TLV: 0.2 ppm as TWA; (ACGIH 2006).
MAK: skin absorption (H);
Carcinogen category: 3B;
(DFG 2006).
OSHA PEL: TWA 1 mg/m³ (0.2 ppm)
NIOSH REL: TWA 1 mg/m³ (0.2 ppm)
NIOSH IDLH: 100 mg/m³ See: 92524

Routes of Exposure:
The substance can be absorbed into the body by inhalation, through the skin and by ingestion.

Inhalation Risk:
A harmful concentration of airborne particles can be reached quickly when dispersed

Effects of Short-Term Exposure:
The substance is irritating to the eyes , the skin and the respiratory tract .

Effects of Long-Term or Repeated Exposure:
The substance may have effects on the liver and nervous system , resulting in impaired functions .

Physical
Properties

Boiling point: 256°C
Melting point: 70°C
Relative density (water = 1): 1.04
Solubility in water, g/100 ml at 20°C: 0.0004
Vapour pressure, Pa at 25°C: 1.19
Relative vapour density (air = 1): 5.3

Relative density of the vapour/air-mixture at 20°C (air = 1): 1.0
Flash point: 113°C c.c
Auto-ignition temperature: 540°C
Explosive limits, vol% in air: 0.6 (at 111°C) - 5.8 (at 166°C)
Octanol/water partition coefficient as log Pow: 3.16/4.09

Environmental
Data

The substance is very toxic to aquatic organisms. Bioaccumulation of this chemical may occur along the food chain, for example in plants. It is strongly advised that this substance does not enter the environment.

N O T E S

Do NOT take working clothes home.

Transport Emergency Card: TEC (R)-90GM7-III
NFPA Code: H 1; F 1; R 0;
Card has been partially updated in November 2008: see Packaging & labelling.

ADDITIONAL INFORMATION

ICSC: 0106	BIPHENYL
(C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE:

Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.