1,1-Dichloroethene
1,1-Dichloroethylene
VDC
C2H2Cl2 / H2C=CCl2
Molecular mass: 97
ICSC # 0083
CAS # 75-35-4
RTECS # KV9275000
UN # 1303 (stabilized)
EC # 602-025-00-8
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Types of Hazard/ Exposure
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Acute Hazards/ Symptoms
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Prevention
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First Aid/
Fire Fighting
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FIRE
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Extremely flammable.
Gives off irritating or toxic fumes (or gases) in a fire.
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NO open flames, NO sparks, and NO smoking.
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Powder, water spray, foam, carbon dioxide.
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Explosion
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Vapour/air mixtures are explosive.
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Closed system, ventilation, explosion-proof electrical equipment and lighting.
Use non-sparking handtools.
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In case of fire: keep drums, etc., cool by spraying with water.
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Exposure
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PREVENT GENERATION OF MISTS!
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•Inhalation
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Dizziness.
Drowsiness.
Unconsciousness.
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Ventilation, local exhaust, or breathing protection.
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Fresh air, rest.
Artificial respiration if indicated.
Refer for medical attention.
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•Skin
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Redness.
Pain.
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Protective gloves.
Protective clothing.
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Remove contaminated clothes.
Rinse and then wash skin with water and soap.
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•Eyes
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Redness.
Pain.
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Safety goggles,
or eye protection in combination with breathing protection.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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•Ingestion
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Abdominal pain.
Sore throat.
(Further see Inhalation).
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Do not eat, drink, or smoke during work.
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Rinse mouth.
Do NOT induce vomiting.
Give plenty of water to drink.
Rest.
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Spillage Disposal
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Storage
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Packaging & Labelling
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Evacuate danger area!
Consult an expert!
Remove all ignition sources.
Collect leaking and spilled liquid in sealable containers as far as possible.
Absorb remaining liquid in sand or inert absorbent and remove to safe place.
Do NOT wash away into sewer.
Do NOT let this chemical enter the environment.
Personal protection: complete protective clothing including self-contained breathing apparatus.
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Fireproof.
Provision to contain effluent from fire extinguishing.
Separated from
incompatible materials
(see Chemical Dangers).
Cool.
Keep in the dark.
Store only if stabilized.
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Airtight.
Unbreakable packaging; put breakable packaging into closed unbreakable container.
Marine pollutant.
Note: D
F+ symbol
Xn symbol
R: 12-20-40
S: 2-7-16-29-36/37-46
UN Hazard Class: 3
UN Packing Group: I
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Important Data
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Physical State; Appearance:
VOLATILE COLOURLESS LIQUID
, WITH CHARACTERISTIC ODOUR.
Physical Dangers:
The vapour is heavier than air
and may travel along the ground; distant ignition possible.
Vinylidine chloride monomer vapours are uninhibited and may form polymers in vents or flame arresters of storage tanks, resulting in blockage of vents.
Chemical Dangers:
The substance can readily form explosive peroxides.
The substance willl polymerize readily
due to heating or
under the influence of oxygen, sunlight, copper or aluminium,
with fire or explosion hazard.
May explode on heating or on contact with flames.
The substance decomposes
on burning
producing
toxic and corrosive fumes
(
hydrogen chloride
,
phosgene
).
Reacts violently with oxidants.
Occupational Exposure Limits:
TLV: 5 ppm as TWA; A4 (not classifiable as a human carcinogen); (ACGIH 2004).
MAK: 2 ppm, 8.0 mg/m3
Peak limitation category: II(2); Carcinogen category: 3B; Pregnancy risk group: C;
(DFG 2004).
OSHA PEL: none
NIOSH REL: Ca See Appendix A
NIOSH IDLH: Ca N.D. See: IDLH INDEX
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Routes of Exposure:
The substance can be absorbed into the body
by inhalation
and
by ingestion.
Inhalation Risk:
A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20°C.
Effects of Short-Term Exposure:
The substance
irritates
the eyes,
the skin and
the respiratory tract.
Swallowing the liquid may cause aspiration into the lungs with the risk of chemical pneumonitis.
Exposure at high levels could cause lowering of consciousness.
Effects of Long-Term or Repeated Exposure:
Repeated or prolonged contact with skin may cause dermatitis.
The substance may have effects on the
kidneys
and
liver
.
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Physical
Properties
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Boiling point: 32°C
Melting point: -122°C
Relative density (water = 1): 1.2
Solubility in water, g/100 ml at 25°C: 0.25
Vapour pressure, kPa at 20°C: 66.5
Relative vapour density (air = 1): 3.3
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Relative density of the vapour/air-mixture at 20°C (air = 1): 2.5
Flash point:
-25°C c.c.
Auto-ignition temperature: 570°C
Explosive limits, vol% in air: 5.6-16
Octanol/water partition coefficient as log Pow: 1.32
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Environmental
Data
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The substance is harmful to aquatic organisms.
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N O T E S
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Depending on the degree of exposure, periodic medical examination is suggested.
An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert.
The odour warning when the exposure limit value is exceeded is insufficient.
Do NOT use in the vicinity of a fire or a hot surface, or during welding.
Card has been partly updated October 2004 and in April 2005. See section Occupational Exposure Limits.
Transport Emergency Card: TEC (R)-30S1303
NFPA Code: H2; F4; R2;
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ADDITIONAL INFORMATION
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ICSC: 0083
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VINYLIDENE CHLORIDE
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(C) IPCS, CEC, 1994
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IMPORTANT LEGAL NOTICE:
Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH,
the CEC or the IPCS is responsible for the use which might be made of this
information. This card contains the collective views of the IPCS Peer Review Committee and may
not reflect in all cases all the detailed requirements included in national legislation
on the subject. The user should verify compliance of the cards with the relevant legislation
in the country of use.
The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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